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The effect of polycations on early cement paste

Pochard, I.; Labbez, C.; Nonat, A.; Vija, H. and Jönsson, Bo LU (2010) In Cement and Concrete Research 40(10). p.1488-1494
Abstract
This paper studies the possibility for improving the ductility of cement based materials by means of oligocationic additives. Actually, the setting of cement is due to ionic correlation forces between highly negatively charged C-S-H nanoparticles throughout a calcium rich solution. The main drawback of this strong attraction is its very short range that results in low elastic deformation of hydrated cementitious materials. A way to enlarge the attraction range between C-S-H particles would be to add cationic oligomers that would compete with calcium ions modifying the ionic correlation forces via a bridging mechanism of longer range, which could lead to a more ductile material. The studied parameters were the polymerization degree, the... (More)
This paper studies the possibility for improving the ductility of cement based materials by means of oligocationic additives. Actually, the setting of cement is due to ionic correlation forces between highly negatively charged C-S-H nanoparticles throughout a calcium rich solution. The main drawback of this strong attraction is its very short range that results in low elastic deformation of hydrated cementitious materials. A way to enlarge the attraction range between C-S-H particles would be to add cationic oligomers that would compete with calcium ions modifying the ionic correlation forces via a bridging mechanism of longer range, which could lead to a more ductile material. The studied parameters were the polymerization degree, the separation distance between the charged monomers and the balance between oligocations and monovalent and divalent cations in the solution. The results, both experimental and numerical by Monte Carlo (MC) simulations, demonstrate that cationic oligomers can compete with calcium cations as counterions to the C-S-H surface. The cohesive forces between C-S-H surfaces, calculated by MC simulations, show an interesting behaviour where range and, magnitude can be tuned with oligomer concentration, polymerization degree and line charge density. Thus, it seems possible to modulate the ductility and critical strain of cement by addition of cationic oligomers. (C) 2010 Elsevier Ltd. All rights reserved. (Less)
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Bridging force, Tensile properties, Cement paste, Polymers
in
Cement and Concrete Research
volume
40
issue
10
pages
1488 - 1494
publisher
Elsevier
external identifiers
  • wos:000281494200004
  • scopus:77955473622
ISSN
0008-8846
DOI
10.1016/j.cemconres.2010.06.002
language
English
LU publication?
yes
id
59cd7447-fc5e-43fc-a19d-dbfd91603b97 (old id 1672454)
date added to LUP
2010-09-23 14:02:24
date last changed
2018-05-29 11:47:11
@article{59cd7447-fc5e-43fc-a19d-dbfd91603b97,
  abstract     = {This paper studies the possibility for improving the ductility of cement based materials by means of oligocationic additives. Actually, the setting of cement is due to ionic correlation forces between highly negatively charged C-S-H nanoparticles throughout a calcium rich solution. The main drawback of this strong attraction is its very short range that results in low elastic deformation of hydrated cementitious materials. A way to enlarge the attraction range between C-S-H particles would be to add cationic oligomers that would compete with calcium ions modifying the ionic correlation forces via a bridging mechanism of longer range, which could lead to a more ductile material. The studied parameters were the polymerization degree, the separation distance between the charged monomers and the balance between oligocations and monovalent and divalent cations in the solution. The results, both experimental and numerical by Monte Carlo (MC) simulations, demonstrate that cationic oligomers can compete with calcium cations as counterions to the C-S-H surface. The cohesive forces between C-S-H surfaces, calculated by MC simulations, show an interesting behaviour where range and, magnitude can be tuned with oligomer concentration, polymerization degree and line charge density. Thus, it seems possible to modulate the ductility and critical strain of cement by addition of cationic oligomers. (C) 2010 Elsevier Ltd. All rights reserved.},
  author       = {Pochard, I. and Labbez, C. and Nonat, A. and Vija, H. and Jönsson, Bo},
  issn         = {0008-8846},
  keyword      = {Bridging force,Tensile properties,Cement paste,Polymers},
  language     = {eng},
  number       = {10},
  pages        = {1488--1494},
  publisher    = {Elsevier},
  series       = {Cement and Concrete Research},
  title        = {The effect of polycations on early cement paste},
  url          = {http://dx.doi.org/10.1016/j.cemconres.2010.06.002},
  volume       = {40},
  year         = {2010},
}