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A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

Jarenmark, Martin LU ; Turitsyna, Elena A.; Haukka, Matti; Shteinman, Albert A. and Nordlander, Ebbe LU (2010) In New Journal of Chemistry 34(10). p.2118-2121
Abstract
Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
New Journal of Chemistry
volume
34
issue
10
pages
2118 - 2121
publisher
Royal Society of Chemistry
external identifiers
  • wos:000282219600009
  • scopus:77957802674
ISSN
1369-9261
DOI
10.1039/c0nj00293c
language
English
LU publication?
yes
id
8ea962e6-b038-4d36-86eb-5d9a4c57c10d (old id 1694580)
date added to LUP
2010-10-26 10:29:12
date last changed
2018-05-29 10:21:00
@article{8ea962e6-b038-4d36-86eb-5d9a4c57c10d,
  abstract     = {Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.},
  author       = {Jarenmark, Martin and Turitsyna, Elena A. and Haukka, Matti and Shteinman, Albert A. and Nordlander, Ebbe},
  issn         = {1369-9261},
  language     = {eng},
  number       = {10},
  pages        = {2118--2121},
  publisher    = {Royal Society of Chemistry},
  series       = {New Journal of Chemistry},
  title        = {A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide},
  url          = {http://dx.doi.org/10.1039/c0nj00293c},
  volume       = {34},
  year         = {2010},
}