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Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts

Grasselli, R. K. ; Lugmair, C. G. ; Volpe Jr., A. F. ; Andersson, Arne LU and Burrington, J.D. (2010) In Catalysis Today 157(1-4). p.33-38
Abstract
Selective doping of (M1) Mo7.8V1.2NbTe0.94O28.9 and (M2) Mo4.67V1.33Te1.82O19.82 phases with P significantly enhance acrylic acid yields (2-15%) in propane/propylene oxidation. Amorphous overlayers (Te-molybdate) seriously inhibit acrylic acid formation. Detailed mechanisms are presented.
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
propylene, M1/M2, propane, acrylic acid
in
Catalysis Today
volume
157
issue
1-4
pages
33 - 38
publisher
Elsevier
external identifiers
  • wos:000284502000006
  • scopus:78049245357
ISSN
0920-5861
DOI
10.1016/j.cattod.2010.01.044
language
English
LU publication?
yes
id
682839cc-1fc3-4488-8acc-0945eba4be89 (old id 1731160)
date added to LUP
2016-04-01 13:55:44
date last changed
2023-11-13 00:04:34
@article{682839cc-1fc3-4488-8acc-0945eba4be89,
  abstract     = {{Selective doping of (M1) Mo7.8V1.2NbTe0.94O28.9 and (M2) Mo4.67V1.33Te1.82O19.82 phases with P significantly enhance acrylic acid yields (2-15%) in propane/propylene oxidation. Amorphous overlayers (Te-molybdate) seriously inhibit acrylic acid formation. Detailed mechanisms are presented.}},
  author       = {{Grasselli, R. K. and Lugmair, C. G. and Volpe Jr., A. F. and Andersson, Arne and Burrington, J.D.}},
  issn         = {{0920-5861}},
  keywords     = {{propylene; M1/M2; propane; acrylic acid}},
  language     = {{eng}},
  number       = {{1-4}},
  pages        = {{33--38}},
  publisher    = {{Elsevier}},
  series       = {{Catalysis Today}},
  title        = {{Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts}},
  url          = {{http://dx.doi.org/10.1016/j.cattod.2010.01.044}},
  doi          = {{10.1016/j.cattod.2010.01.044}},
  volume       = {{157}},
  year         = {{2010}},
}