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Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts

Grasselli, R. K.; Lugmair, C. G.; Volpe Jr., A. F.; Andersson, Arne LU and Burrington, J.D. (2010) In Catalysis Today 157(1-4). p.33-38
Abstract
Selective doping of (M1) Mo7.8V1.2NbTe0.94O28.9 and (M2) Mo4.67V1.33Te1.82O19.82 phases with P significantly enhance acrylic acid yields (2-15%) in propane/propylene oxidation. Amorphous overlayers (Te-molybdate) seriously inhibit acrylic acid formation. Detailed mechanisms are presented.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
propylene, M1/M2, propane, acrylic acid
in
Catalysis Today
volume
157
issue
1-4
pages
33 - 38
publisher
Elsevier
external identifiers
  • wos:000284502000006
  • scopus:78049245357
ISSN
0920-5861
DOI
10.1016/j.cattod.2010.01.044
language
English
LU publication?
yes
id
682839cc-1fc3-4488-8acc-0945eba4be89 (old id 1731160)
date added to LUP
2010-12-07 16:02:33
date last changed
2018-07-08 03:41:40
@article{682839cc-1fc3-4488-8acc-0945eba4be89,
  abstract     = {Selective doping of (M1) Mo7.8V1.2NbTe0.94O28.9 and (M2) Mo4.67V1.33Te1.82O19.82 phases with P significantly enhance acrylic acid yields (2-15%) in propane/propylene oxidation. Amorphous overlayers (Te-molybdate) seriously inhibit acrylic acid formation. Detailed mechanisms are presented.},
  author       = {Grasselli, R. K. and Lugmair, C. G. and Volpe Jr., A. F. and Andersson, Arne and Burrington, J.D.},
  issn         = {0920-5861},
  keyword      = {propylene,M1/M2,propane,acrylic acid},
  language     = {eng},
  number       = {1-4},
  pages        = {33--38},
  publisher    = {Elsevier},
  series       = {Catalysis Today},
  title        = {Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts},
  url          = {http://dx.doi.org/10.1016/j.cattod.2010.01.044},
  volume       = {157},
  year         = {2010},
}