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Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}2 (H3L = trans-aconitic acid)

Kostakis, George E. ; Nordlander, Ebbe LU ; Tsipis, Athanassios C. ; Haukka, Matti and Plakatouras, John C. (2011) In Inorganic Chemistry Communications 14(1). p.87-91
Abstract
The reaction of Zn(NO3)(2)center dot 3(H2O) with trans-aconitic acid (H3L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}(2). The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented. (C) 2010 Elsevier B.V. All rights reserved.
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Hexameric water cluster, Zinc(II), 3D metal-supramolecular, architecture, H-bond, Crystal structure
in
Inorganic Chemistry Communications
volume
14
issue
1
pages
87 - 91
publisher
Elsevier
external identifiers
  • wos:000287269000022
  • scopus:78651266797
ISSN
1879-0259
DOI
10.1016/j.inoche.2010.09.038
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
b1f85e55-d946-42c4-a1f6-54a2ba236ba7 (old id 1872844)
date added to LUP
2016-04-01 09:49:18
date last changed
2020-09-02 01:00:30
@article{b1f85e55-d946-42c4-a1f6-54a2ba236ba7,
  abstract     = {The reaction of Zn(NO3)(2)center dot 3(H2O) with trans-aconitic acid (H3L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}(2). The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented. (C) 2010 Elsevier B.V. All rights reserved.},
  author       = {Kostakis, George E. and Nordlander, Ebbe and Tsipis, Athanassios C. and Haukka, Matti and Plakatouras, John C.},
  issn         = {1879-0259},
  language     = {eng},
  number       = {1},
  pages        = {87--91},
  publisher    = {Elsevier},
  series       = {Inorganic Chemistry Communications},
  title        = {Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}2 (H3L = trans-aconitic acid)},
  url          = {http://dx.doi.org/10.1016/j.inoche.2010.09.038},
  doi          = {10.1016/j.inoche.2010.09.038},
  volume       = {14},
  year         = {2011},
}