Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspi ro[5.5]undecane
(2011) In Acta Crystallographica Section E: Structure Reports Online 67(Pt 6). p.719-720- Abstract
- The AuI atom in the title compound, [Au(C21H24N2)(2)](C24H20B5O6), adopts a slightly distorted linear AuC2 coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3 (6)degrees. In the crystal, the components are linked by weak C-H...O hydrogen bonds.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1985689
- author
- Mohlmann, Lennart ; Wendt, Ola LU and Johnson, Magnus LU
- organization
- publishing date
- 2011
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Acta Crystallographica Section E: Structure Reports Online
- volume
- 67
- issue
- Pt 6
- pages
- 719 - 720
- publisher
- International Union of Crystallography
- external identifiers
-
- wos:000291215800054
- scopus:79958019246
- pmid:21754618
- pmid:21754618
- ISSN
- 1600-5368
- DOI
- 10.1107/S1600536811016357
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- 0447a0ef-fe38-425a-b754-18602caf9488 (old id 1985689)
- date added to LUP
- 2016-04-01 12:59:30
- date last changed
- 2022-01-27 08:40:32
@article{0447a0ef-fe38-425a-b754-18602caf9488, abstract = {{The AuI atom in the title compound, [Au(C21H24N2)(2)](C24H20B5O6), adopts a slightly distorted linear AuC2 coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3 (6)degrees. In the crystal, the components are linked by weak C-H...O hydrogen bonds.}}, author = {{Mohlmann, Lennart and Wendt, Ola and Johnson, Magnus}}, issn = {{1600-5368}}, language = {{eng}}, number = {{Pt 6}}, pages = {{719--720}}, publisher = {{International Union of Crystallography}}, series = {{Acta Crystallographica Section E: Structure Reports Online}}, title = {{Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspi ro[5.5]undecane}}, url = {{http://dx.doi.org/10.1107/S1600536811016357}}, doi = {{10.1107/S1600536811016357}}, volume = {{67}}, year = {{2011}}, }