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Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspi ro[5.5]undecane

Mohlmann, Lennart; Wendt, Ola LU and Johnson, Magnus LU (2011) In Acta Crystallographica Section E: Structure Reports Online 67(Pt 6). p.719-720
Abstract
The AuI atom in the title compound, [Au(C21H24N2)(2)](C24H20B5O6), adopts a slightly distorted linear AuC2 coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3 (6)degrees. In the crystal, the components are linked by weak C-H...O hydrogen bonds.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
67
issue
Pt 6
pages
719 - 720
publisher
Wiley-Blackwell
external identifiers
  • wos:000291215800054
  • scopus:79958019246
  • pmid:21754618
ISSN
1600-5368
DOI
10.1107/S1600536811016357
language
English
LU publication?
yes
id
0447a0ef-fe38-425a-b754-18602caf9488 (old id 1985689)
date added to LUP
2011-07-06 12:10:10
date last changed
2017-08-27 04:30:21
@article{0447a0ef-fe38-425a-b754-18602caf9488,
  abstract     = {The AuI atom in the title compound, [Au(C21H24N2)(2)](C24H20B5O6), adopts a slightly distorted linear AuC2 coordination geometry arising from its coordination by two mesitylenic N-heterocyclic carbene ligands, forming an overall cationic complex. The dihedral angle between the imidazole rings is 57.3 (6)degrees. In the crystal, the components are linked by weak C-H...O hydrogen bonds.},
  author       = {Mohlmann, Lennart and Wendt, Ola and Johnson, Magnus},
  issn         = {1600-5368},
  language     = {eng},
  number       = {Pt 6},
  pages        = {719--720},
  publisher    = {Wiley-Blackwell},
  series       = {Acta Crystallographica Section E: Structure Reports Online},
  title        = {Bis(1,3-dimesitylimidazolyl)gold(I) 2,4,8,10-tetraphenyl-1,3,5,7,9,11-hexaoxa-2,4,8,10-tetrabora-6-borataspi ro[5.5]undecane},
  url          = {http://dx.doi.org/10.1107/S1600536811016357},
  volume       = {67},
  year         = {2011},
}