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Enantiotopic Discrimination by Coordination-Desymmetrized meso-Ligands

Li, Yutang LU ; Lidskog, Anna LU ; Armengol-Relats, Helena ; Pham, Thanh Huong LU ; Favraud, Antoine ; Nicolas, Maxime ; Dawaigher, Sami LU ; Xiao, Zeyun LU ; Ma, Dayou LU and Lindbäck, Emil LU , et al. (2020) In ChemCatChem 12(6). p.1575-1579
Abstract

The first examples of enantiopure catalysts that are chiral merely due to coordination of different metal ions at enantiotopic positions of an achiral meso-ligand are reported. These catalysts exhibit a pseudo-Cs symmetry and are able to catalyze reactions demanding simultaneous involvement of two catalytic sites. The latter was demonstrated by application in the asymmetric ring-opening of meso-epoxides.

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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
asymmetric ring opening, bissalen, pseudo-meso
in
ChemCatChem
volume
12
issue
6
pages
5 pages
publisher
Wiley-VCH Verlag
external identifiers
  • scopus:85082308128
ISSN
1867-3880
DOI
10.1002/cctc.201902243
language
English
LU publication?
yes
id
1b8ea2b2-c099-4415-9427-e7bec0ada290
date added to LUP
2020-04-03 12:22:34
date last changed
2025-10-14 12:00:48
@article{1b8ea2b2-c099-4415-9427-e7bec0ada290,
  abstract     = {{<p>The first examples of enantiopure catalysts that are chiral merely due to coordination of different metal ions at enantiotopic positions of an achiral meso-ligand are reported. These catalysts exhibit a pseudo-C<sub>s</sub> symmetry and are able to catalyze reactions demanding simultaneous involvement of two catalytic sites. The latter was demonstrated by application in the asymmetric ring-opening of meso-epoxides.</p>}},
  author       = {{Li, Yutang and Lidskog, Anna and Armengol-Relats, Helena and Pham, Thanh Huong and Favraud, Antoine and Nicolas, Maxime and Dawaigher, Sami and Xiao, Zeyun and Ma, Dayou and Lindbäck, Emil and Strand, Daniel and Wärnmark, Kenneth}},
  issn         = {{1867-3880}},
  keywords     = {{asymmetric ring opening; bissalen; pseudo-meso}},
  language     = {{eng}},
  number       = {{6}},
  pages        = {{1575--1579}},
  publisher    = {{Wiley-VCH Verlag}},
  series       = {{ChemCatChem}},
  title        = {{Enantiotopic Discrimination by Coordination-Desymmetrized meso-Ligands}},
  url          = {{http://dx.doi.org/10.1002/cctc.201902243}},
  doi          = {{10.1002/cctc.201902243}},
  volume       = {{12}},
  year         = {{2020}},
}