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Cryostructuration of polymer systems. XXIV. Poly(vinyl alcohol) cryogels filled with particles of a strong anion exchanger: Properties of the composite materials and potential applications

Savina, Irina LU ; Hanora, Amro LU ; Plieva, Fatima LU ; Galaev, Igor LU ; Mattiasson, Bo LU and Lozinsky, Vladimir I (2005) In Journal of Applied Polymer Science 95(3). p.529-538
Abstract
A composite material produced from a poly(vinyl alcohol) cryogel with entrapped particles of the strong anion-exchange resin Amberlite is presented. The properties of the composite material depended strongly on whether the resin was used in OH- form or Cl- form. The ion-exchange filler in OH- form caused both a significant reinforcement of the composite material and an increase in the gel fusion temperature. These effects were thought to be associated with the additional ionic bonding between the continuous and disperse phases. Beads 200-600 m in size were prepared from the composite material and used in expanded-bed ion-exchange chromatography for the capture of the negatively charged solutes benzoate and lactate from the suspension of... (More)
A composite material produced from a poly(vinyl alcohol) cryogel with entrapped particles of the strong anion-exchange resin Amberlite is presented. The properties of the composite material depended strongly on whether the resin was used in OH- form or Cl- form. The ion-exchange filler in OH- form caused both a significant reinforcement of the composite material and an increase in the gel fusion temperature. These effects were thought to be associated with the additional ionic bonding between the continuous and disperse phases. Beads 200-600 m in size were prepared from the composite material and used in expanded-bed ion-exchange chromatography for the capture of the negatively charged solutes benzoate and lactate from the suspension of negatively charged cells. The plausibility of the approach has been demonstrated on model systems composed of yeast cells and benzoate and with a real fermentation broth produced after lactic acid fermentation. (Less)
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author
; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
gelation, composites, ion exchangers
in
Journal of Applied Polymer Science
volume
95
issue
3
pages
529 - 538
publisher
John Wiley & Sons Inc.
external identifiers
  • wos:000226180900006
  • scopus:12344292367
ISSN
1097-4628
DOI
10.1002/app.21227
language
English
LU publication?
yes
id
1be7ba47-7ab7-44c0-adde-becb052dc9f6 (old id 141675)
date added to LUP
2016-04-01 11:39:56
date last changed
2022-01-26 08:22:32
@article{1be7ba47-7ab7-44c0-adde-becb052dc9f6,
  abstract     = {{A composite material produced from a poly(vinyl alcohol) cryogel with entrapped particles of the strong anion-exchange resin Amberlite is presented. The properties of the composite material depended strongly on whether the resin was used in OH- form or Cl- form. The ion-exchange filler in OH- form caused both a significant reinforcement of the composite material and an increase in the gel fusion temperature. These effects were thought to be associated with the additional ionic bonding between the continuous and disperse phases. Beads 200-600 m in size were prepared from the composite material and used in expanded-bed ion-exchange chromatography for the capture of the negatively charged solutes benzoate and lactate from the suspension of negatively charged cells. The plausibility of the approach has been demonstrated on model systems composed of yeast cells and benzoate and with a real fermentation broth produced after lactic acid fermentation.}},
  author       = {{Savina, Irina and Hanora, Amro and Plieva, Fatima and Galaev, Igor and Mattiasson, Bo and Lozinsky, Vladimir I}},
  issn         = {{1097-4628}},
  keywords     = {{gelation; composites; ion exchangers}},
  language     = {{eng}},
  number       = {{3}},
  pages        = {{529--538}},
  publisher    = {{John Wiley & Sons Inc.}},
  series       = {{Journal of Applied Polymer Science}},
  title        = {{Cryostructuration of polymer systems. XXIV. Poly(vinyl alcohol) cryogels filled with particles of a strong anion exchanger: Properties of the composite materials and potential applications}},
  url          = {{http://dx.doi.org/10.1002/app.21227}},
  doi          = {{10.1002/app.21227}},
  volume       = {{95}},
  year         = {{2005}},
}