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Performance of nanoporous carbon membrane for hydrogen recovery

Al-Rabiah, Abdulrahman A. ; Ajbar, Abdelhamid M. ; Soliman, Moustafa A. and Abdelaziz, Omar Y. LU (2018) In Journal of the Chemical Society of Pakistan 40(1). p.43-51
Abstract

The aim of this work is to study the performance of nanoporous carbon membrane for hydrogen recovery from off-gas streams. The study is based on a rigorous mathematical model which can predict the performance of nanoporous selective surface flow (SSF) carbon membrane. Basically, the developed model is based on two transport mechanisms: the dusty gas flow through porous media and the surface adsorption-diffusion. The model was employed to simulate the hydrogen recovery from off-gas stream using SSF carbon membrane at different operating conditions. The separation performance of hydrogen-hydrocarbon mixture by nanoporous carbon membrane was evaluated and described. A comparison between the model simulation and the experimental data... (More)

The aim of this work is to study the performance of nanoporous carbon membrane for hydrogen recovery from off-gas streams. The study is based on a rigorous mathematical model which can predict the performance of nanoporous selective surface flow (SSF) carbon membrane. Basically, the developed model is based on two transport mechanisms: the dusty gas flow through porous media and the surface adsorption-diffusion. The model was employed to simulate the hydrogen recovery from off-gas stream using SSF carbon membrane at different operating conditions. The separation performance of hydrogen-hydrocarbon mixture by nanoporous carbon membrane was evaluated and described. A comparison between the model simulation and the experimental data related to hydrogen recovery from off-gas streams shows good agreement. A parametric study is further carried out to show the effects of pressure at the membrane feed and permeate sides. The effects of flow-rate and type of sweep gas at the membrane permeate side on hydrogen recovery are also shown. SSF membrane illustrates a significant potential to be used for hydrogen recovery from refinery off-gas streams.

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author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Dusty gas model, Hydrogen gas transport, Hydrogen production, Hydrogen-hydrocarbon separation, Membranes, Selective surface flow
in
Journal of the Chemical Society of Pakistan
volume
40
issue
1
pages
9 pages
publisher
Chemical Society of Pakistan
external identifiers
  • scopus:85047859724
ISSN
0253-5106
language
English
LU publication?
yes
id
1e2d8692-c4b0-42b4-9d2a-24d20c546395
date added to LUP
2018-06-15 15:15:27
date last changed
2023-09-08 03:07:52
@article{1e2d8692-c4b0-42b4-9d2a-24d20c546395,
  abstract     = {{<p>The aim of this work is to study the performance of nanoporous carbon membrane for hydrogen recovery from off-gas streams. The study is based on a rigorous mathematical model which can predict the performance of nanoporous selective surface flow (SSF) carbon membrane. Basically, the developed model is based on two transport mechanisms: the dusty gas flow through porous media and the surface adsorption-diffusion. The model was employed to simulate the hydrogen recovery from off-gas stream using SSF carbon membrane at different operating conditions. The separation performance of hydrogen-hydrocarbon mixture by nanoporous carbon membrane was evaluated and described. A comparison between the model simulation and the experimental data related to hydrogen recovery from off-gas streams shows good agreement. A parametric study is further carried out to show the effects of pressure at the membrane feed and permeate sides. The effects of flow-rate and type of sweep gas at the membrane permeate side on hydrogen recovery are also shown. SSF membrane illustrates a significant potential to be used for hydrogen recovery from refinery off-gas streams.</p>}},
  author       = {{Al-Rabiah, Abdulrahman A. and Ajbar, Abdelhamid M. and Soliman, Moustafa A. and Abdelaziz, Omar Y.}},
  issn         = {{0253-5106}},
  keywords     = {{Dusty gas model; Hydrogen gas transport; Hydrogen production; Hydrogen-hydrocarbon separation; Membranes; Selective surface flow}},
  language     = {{eng}},
  month        = {{01}},
  number       = {{1}},
  pages        = {{43--51}},
  publisher    = {{Chemical Society of Pakistan}},
  series       = {{Journal of the Chemical Society of Pakistan}},
  title        = {{Performance of nanoporous carbon membrane for hydrogen recovery}},
  volume       = {{40}},
  year         = {{2018}},
}