Local structure of photoexcited bimetallic complexes refined by quantitative XANES analysis
(2011) In Journal of Electron Spectroscopy and Related Phenomena 184(3-6). p.125-128- Abstract
- Photoexcited states of a pyrazolate bridged PtPt dimer and a supramolecular RuCo complex with bipyridine-type ligands were studied using the pump-and-probe X-ray absorption spectroscopy method. The local structure refinement based on the fitting of XANES difference spectra has been performed. The theoretical analysis included the full multiple scattering calculations and the multidimensional interpolation of spectra as a function of structural parameters. The influence of possible correlations between the fraction of molecules in the photoexcited state and structural parameters is discussed. (C) 2011 Elsevier B.V. All rights reserved.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2032250
- author
- Smolentsev, Grigory LU ; Canton, Sophie LU ; Lockard, J. V. ; Sundström, Villy LU and Chen, L. X.
- organization
- publishing date
- 2011
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- X-ray transient absorption, XANES, Ultrafast X-ray spectroscopy
- in
- Journal of Electron Spectroscopy and Related Phenomena
- volume
- 184
- issue
- 3-6
- pages
- 125 - 128
- publisher
- Elsevier
- external identifiers
-
- wos:000292173400009
- scopus:79957591319
- ISSN
- 0368-2048
- DOI
- 10.1016/j.elspec.2011.01.010
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060), Max-laboratory (011012005)
- id
- 5d471778-9bb6-46b2-b65d-26b85d028bf2 (old id 2032250)
- date added to LUP
- 2016-04-01 13:36:02
- date last changed
- 2023-09-17 02:21:13
@article{5d471778-9bb6-46b2-b65d-26b85d028bf2, abstract = {{Photoexcited states of a pyrazolate bridged PtPt dimer and a supramolecular RuCo complex with bipyridine-type ligands were studied using the pump-and-probe X-ray absorption spectroscopy method. The local structure refinement based on the fitting of XANES difference spectra has been performed. The theoretical analysis included the full multiple scattering calculations and the multidimensional interpolation of spectra as a function of structural parameters. The influence of possible correlations between the fraction of molecules in the photoexcited state and structural parameters is discussed. (C) 2011 Elsevier B.V. All rights reserved.}}, author = {{Smolentsev, Grigory and Canton, Sophie and Lockard, J. V. and Sundström, Villy and Chen, L. X.}}, issn = {{0368-2048}}, keywords = {{X-ray transient absorption; XANES; Ultrafast X-ray spectroscopy}}, language = {{eng}}, number = {{3-6}}, pages = {{125--128}}, publisher = {{Elsevier}}, series = {{Journal of Electron Spectroscopy and Related Phenomena}}, title = {{Local structure of photoexcited bimetallic complexes refined by quantitative XANES analysis}}, url = {{http://dx.doi.org/10.1016/j.elspec.2011.01.010}}, doi = {{10.1016/j.elspec.2011.01.010}}, volume = {{184}}, year = {{2011}}, }