Interfacial Molecular Imprinting in Nanoparticle-Stabilized Emulsions.
Shen, Xiantao LU and Ye, Lei LU
(2011)
In Macromolecules
44(14).
p.5631-5637
- Abstract
- A new interfacial nano and molecular imprinting approach is developed to prepare spherical molecularly imprinted polymers with well-controlled hierarchical structures. This method is based on Pickering emulsion polymerization using template-modified colloidal particles. The interfacial imprinting is carried out in particle-stabilized oil-in-water emulsions, where the molecular template is presented on the surface of silica nanoparticles during the polymerization of the monomer phase. After polymerization, the template-modified silica nanoparticles are removed from the new spherical particles to leave tiny indentations decorated with molecularly imprinted sites. The imprinted microspheres prepared using the new interfacial nano and... (More)
- A new interfacial nano and molecular imprinting approach is developed to prepare spherical molecularly imprinted polymers with well-controlled hierarchical structures. This method is based on Pickering emulsion polymerization using template-modified colloidal particles. The interfacial imprinting is carried out in particle-stabilized oil-in-water emulsions, where the molecular template is presented on the surface of silica nanoparticles during the polymerization of the monomer phase. After polymerization, the template-modified silica nanoparticles are removed from the new spherical particles to leave tiny indentations decorated with molecularly imprinted sites. The imprinted microspheres prepared using the new interfacial nano and molecular imprinting have very interesting features: a well-controlled hierarchical structure composed of large pores decorated with easily accessible molecular binding sites, group selectivity toward a series of chemicals having a common structural moiety (epitopes), and a hydrophilic surface that enables the MIPs to be used under aqueous conditions. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2058377
- author
- Shen, Xiantao
LU
and Ye, Lei
LU
- organization
- publishing date
- 2011
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Macromolecules
- volume
- 44
- issue
- 14
- pages
- 5631 - 5637
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000292850100013
- scopus:79960534568
- pmid:21779131
- ISSN
- 0024-9297
- DOI
- 10.1021/ma200837n
- language
- English
- LU publication?
- yes
- id
- 0db4cbf4-84fd-4a5a-b272-ea248264928b (old id 2058377)
- alternative location
- http://www.ncbi.nlm.nih.gov/pubmed/21779131?dopt=Abstract
- date added to LUP
- 2016-04-01 10:23:48
- date last changed
- 2022-04-27 21:35:15
@article{0db4cbf4-84fd-4a5a-b272-ea248264928b,
abstract = {{A new interfacial nano and molecular imprinting approach is developed to prepare spherical molecularly imprinted polymers with well-controlled hierarchical structures. This method is based on Pickering emulsion polymerization using template-modified colloidal particles. The interfacial imprinting is carried out in particle-stabilized oil-in-water emulsions, where the molecular template is presented on the surface of silica nanoparticles during the polymerization of the monomer phase. After polymerization, the template-modified silica nanoparticles are removed from the new spherical particles to leave tiny indentations decorated with molecularly imprinted sites. The imprinted microspheres prepared using the new interfacial nano and molecular imprinting have very interesting features: a well-controlled hierarchical structure composed of large pores decorated with easily accessible molecular binding sites, group selectivity toward a series of chemicals having a common structural moiety (epitopes), and a hydrophilic surface that enables the MIPs to be used under aqueous conditions.}},
author = {{Shen, Xiantao and Ye, Lei}},
issn = {{0024-9297}},
language = {{eng}},
number = {{14}},
pages = {{5631--5637}},
publisher = {{The American Chemical Society (ACS)}},
series = {{Macromolecules}},
title = {{Interfacial Molecular Imprinting in Nanoparticle-Stabilized Emulsions.}},
url = {{http://dx.doi.org/10.1021/ma200837n}},
doi = {{10.1021/ma200837n}},
volume = {{44}},
year = {{2011}},
}