Multi-component self-assembly of molecule based materials by coordination networks and weak intermolecular synthons
(2011) In CrystEngComm 13(19). p.5813-5817- Abstract
- The coordination polymer [Fe(SCN)(2)(1,2-bis(4-pyridylmethylene)hydrazine)(2)](n) [Fe(phenanthroline)(3)](2n)(ClO4)(2n)center dot n1,2-bis(4-pyridylmethylene)hydrazine center dot 4nH(2)O 1 was crystallised from a MeOH/MeCN solution and the structure consists of layered (4,4) 2D-nets with supramolecular ([Fe(phen)(3)](2)bphz)(4+) units in the pores and disordered water and perchlorate anions. The same supramolecular motif could be independently prepared as [Fe(phen)(3)](2)center dot bphz(ClO4)(4)center dot xMeOH(2), and the [Ru(phenanthroline)(3)](2+) compound 3, isostructural to 1, was also prepared although a complete structure determination was prevented by low crystal quality. Compounds 1 and 3 are rare examples of how several large and... (More)
- The coordination polymer [Fe(SCN)(2)(1,2-bis(4-pyridylmethylene)hydrazine)(2)](n) [Fe(phenanthroline)(3)](2n)(ClO4)(2n)center dot n1,2-bis(4-pyridylmethylene)hydrazine center dot 4nH(2)O 1 was crystallised from a MeOH/MeCN solution and the structure consists of layered (4,4) 2D-nets with supramolecular ([Fe(phen)(3)](2)bphz)(4+) units in the pores and disordered water and perchlorate anions. The same supramolecular motif could be independently prepared as [Fe(phen)(3)](2)center dot bphz(ClO4)(4)center dot xMeOH(2), and the [Ru(phenanthroline)(3)](2+) compound 3, isostructural to 1, was also prepared although a complete structure determination was prevented by low crystal quality. Compounds 1 and 3 are rare examples of how several large and different components can be assembled inside a 2D coordination network and provide a concept for multi-component self-assembly. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2187147
- author
- Ghazzali, Mohamed ; Langer, Vratislav ; Larsson, Krister LU and Ohrstrom, Lars
- organization
- publishing date
- 2011
- type
- Contribution to journal
- publication status
- published
- subject
- in
- CrystEngComm
- volume
- 13
- issue
- 19
- pages
- 5813 - 5817
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000294667000031
- scopus:80052771844
- ISSN
- 1466-8033
- DOI
- 10.1039/c1ce05527e
- language
- English
- LU publication?
- yes
- id
- 22f66ead-c943-420b-af86-8440298479e8 (old id 2187147)
- date added to LUP
- 2016-04-01 14:41:23
- date last changed
- 2022-01-28 01:58:12
@article{22f66ead-c943-420b-af86-8440298479e8,
abstract = {{The coordination polymer [Fe(SCN)(2)(1,2-bis(4-pyridylmethylene)hydrazine)(2)](n) [Fe(phenanthroline)(3)](2n)(ClO4)(2n)center dot n1,2-bis(4-pyridylmethylene)hydrazine center dot 4nH(2)O 1 was crystallised from a MeOH/MeCN solution and the structure consists of layered (4,4) 2D-nets with supramolecular ([Fe(phen)(3)](2)bphz)(4+) units in the pores and disordered water and perchlorate anions. The same supramolecular motif could be independently prepared as [Fe(phen)(3)](2)center dot bphz(ClO4)(4)center dot xMeOH(2), and the [Ru(phenanthroline)(3)](2+) compound 3, isostructural to 1, was also prepared although a complete structure determination was prevented by low crystal quality. Compounds 1 and 3 are rare examples of how several large and different components can be assembled inside a 2D coordination network and provide a concept for multi-component self-assembly.}},
author = {{Ghazzali, Mohamed and Langer, Vratislav and Larsson, Krister and Ohrstrom, Lars}},
issn = {{1466-8033}},
language = {{eng}},
number = {{19}},
pages = {{5813--5817}},
publisher = {{Royal Society of Chemistry}},
series = {{CrystEngComm}},
title = {{Multi-component self-assembly of molecule based materials by coordination networks and weak intermolecular synthons}},
url = {{http://dx.doi.org/10.1039/c1ce05527e}},
doi = {{10.1039/c1ce05527e}},
volume = {{13}},
year = {{2011}},
}