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Crosslinked Polyamide Based on Main-Chain Type Polybenzoxazines Derived from a Primary Amine-Functionalized Benzoxazine Monomer

Agag, Tarek; Rodriguez Arza, Carlos LU ; Maurer, Frans LU and Ishida, Hatsuo (2011) In Journal of Polymer Science. Part A, Polymer Chemistry 49(20). p.4335-4342
Abstract
Two types of main-chain type polybenzoxazines with amide and benzoxazine groups as repeating units in the main chain, termed as poly(amide-benzoxazine), have been synthesized. They have been prepared by polycondensation reaction of primary amine-bifunctional benzoxazine with adipoyl and isophthaloyl dichloride using dimethylacetamide as solvent. Additionally, a model reaction is designed from the reaction of 3,3'-(4,4'-methylenebis(4,1-phenylene)) bis(3,4-dihydro-2H-benzo[e][1,3]oxazin-6-amine) with benzoyl chloride. The structures of model compound and polyamides are confirmed by Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (H-1 NMR) spectroscopies. Differential scanning calorimetry and FTIR are also used to... (More)
Two types of main-chain type polybenzoxazines with amide and benzoxazine groups as repeating units in the main chain, termed as poly(amide-benzoxazine), have been synthesized. They have been prepared by polycondensation reaction of primary amine-bifunctional benzoxazine with adipoyl and isophthaloyl dichloride using dimethylacetamide as solvent. Additionally, a model reaction is designed from the reaction of 3,3'-(4,4'-methylenebis(4,1-phenylene)) bis(3,4-dihydro-2H-benzo[e][1,3]oxazin-6-amine) with benzoyl chloride. The structures of model compound and polyamides are confirmed by Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (H-1 NMR) spectroscopies. Differential scanning calorimetry and FTIR are also used to study crosslinking behavior of both the model compound and polymers. Thermal properties of the crosslinked polymers are also studied by thermogravimetric analysis. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 4335-4342, 2011 (Less)
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
crosslinked polyamide, main chain benzoxazine polymer, polymerization, behavior, primary amine-functional benzoxazine
in
Journal of Polymer Science. Part A, Polymer Chemistry
volume
49
issue
20
pages
4335 - 4342
publisher
John Wiley & Sons
external identifiers
  • wos:000295714800005
  • scopus:80052697197
ISSN
0887-624X
DOI
10.1002/pola.24867
language
English
LU publication?
yes
id
9ae308ee-ede1-4815-85e0-e84f4db18ce5 (old id 2212692)
date added to LUP
2011-11-23 13:52:46
date last changed
2017-11-05 04:09:29
@article{9ae308ee-ede1-4815-85e0-e84f4db18ce5,
  abstract     = {Two types of main-chain type polybenzoxazines with amide and benzoxazine groups as repeating units in the main chain, termed as poly(amide-benzoxazine), have been synthesized. They have been prepared by polycondensation reaction of primary amine-bifunctional benzoxazine with adipoyl and isophthaloyl dichloride using dimethylacetamide as solvent. Additionally, a model reaction is designed from the reaction of 3,3'-(4,4'-methylenebis(4,1-phenylene)) bis(3,4-dihydro-2H-benzo[e][1,3]oxazin-6-amine) with benzoyl chloride. The structures of model compound and polyamides are confirmed by Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (H-1 NMR) spectroscopies. Differential scanning calorimetry and FTIR are also used to study crosslinking behavior of both the model compound and polymers. Thermal properties of the crosslinked polymers are also studied by thermogravimetric analysis. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 4335-4342, 2011},
  author       = {Agag, Tarek and Rodriguez Arza, Carlos and Maurer, Frans and Ishida, Hatsuo},
  issn         = {0887-624X},
  keyword      = {crosslinked polyamide,main chain benzoxazine polymer,polymerization,behavior,primary amine-functional benzoxazine},
  language     = {eng},
  number       = {20},
  pages        = {4335--4342},
  publisher    = {John Wiley & Sons},
  series       = {Journal of Polymer Science. Part A, Polymer Chemistry},
  title        = {Crosslinked Polyamide Based on Main-Chain Type Polybenzoxazines Derived from a Primary Amine-Functionalized Benzoxazine Monomer},
  url          = {http://dx.doi.org/10.1002/pola.24867},
  volume       = {49},
  year         = {2011},
}