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Soft X-ray induced oxidation on acrylic acid grafted luminescent silicon quantum dots in ultrahigh vacuum

Chao, Yimin; Wang, Qi; Pietzsch, Annette LU ; Hennies, Franz LU and Ni, Hongjun (2011) In Physica Status Solidi. A: Applications and Materials Science 208(10). p.2424-2429
Abstract
Water soluble acrylic acid grafted luminescent silicon quantum dots (Si-QDs) were prepared by a simplified method. The resulting Si-QDs dissolved in water and showed stable strong luminescence with peaks at 436 and 604 nm. X-ray photoelectron spectroscopy (XPS) was employed to examine the surface electronic states after the synthesis. The co-existence of the Si2p and C1s core levels infers that the acrylic acid has been successfully grafted on the surface of silicon quantum dots. To fit the Si2p spectrum, four components were needed at 99.45, 100.28, 102.21 and 103.24 eV. The first component at 99.45 eV (I) was assigned to Si-Si within the silicon core of the Si-QDs. The second component at 100.28 eV (II) was from Si-C. The third at 102.21... (More)
Water soluble acrylic acid grafted luminescent silicon quantum dots (Si-QDs) were prepared by a simplified method. The resulting Si-QDs dissolved in water and showed stable strong luminescence with peaks at 436 and 604 nm. X-ray photoelectron spectroscopy (XPS) was employed to examine the surface electronic states after the synthesis. The co-existence of the Si2p and C1s core levels infers that the acrylic acid has been successfully grafted on the surface of silicon quantum dots. To fit the Si2p spectrum, four components were needed at 99.45, 100.28, 102.21 and 103.24 eV. The first component at 99.45 eV (I) was assigned to Si-Si within the silicon core of the Si-QDs. The second component at 100.28 eV (II) was from Si-C. The third at 102.21 eV (III) was a sub-oxide state and the fourth at 103.24 eV (IV) was from SiO2 at Si-QDs surface. With an increase in exposure to soft X-ray photons, the intensity ratio of the two peaks within the Si2p region A and B increased from 0.5 to 1.4 while the peak A intensity decreased, and eventually a steady state was reached. This observation is explained in terms of photon-induced oxidation taking place within the surface dangling bonds. As the PL profile for Si-QDs is influenced by the degree of oxidation within the nanocrystal structure, the inducement of oxidation by soft X-rays will play a role in the range of potential applications where such materials could be used - especially within biomedical labelling. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (Less)
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
core levels, quantum dots, silicon, XPS
in
Physica Status Solidi. A: Applications and Materials Science
volume
208
issue
10
pages
2424 - 2429
publisher
Wiley-Blackwell
external identifiers
  • wos:000296618600040
  • scopus:80053997024
ISSN
1862-6300
DOI
10.1002/pssa.201127212
language
English
LU publication?
yes
id
d0299d3b-28b8-4069-aed3-387cc208ab70 (old id 2253121)
date added to LUP
2011-12-21 15:38:51
date last changed
2017-01-01 03:11:46
@article{d0299d3b-28b8-4069-aed3-387cc208ab70,
  abstract     = {Water soluble acrylic acid grafted luminescent silicon quantum dots (Si-QDs) were prepared by a simplified method. The resulting Si-QDs dissolved in water and showed stable strong luminescence with peaks at 436 and 604 nm. X-ray photoelectron spectroscopy (XPS) was employed to examine the surface electronic states after the synthesis. The co-existence of the Si2p and C1s core levels infers that the acrylic acid has been successfully grafted on the surface of silicon quantum dots. To fit the Si2p spectrum, four components were needed at 99.45, 100.28, 102.21 and 103.24 eV. The first component at 99.45 eV (I) was assigned to Si-Si within the silicon core of the Si-QDs. The second component at 100.28 eV (II) was from Si-C. The third at 102.21 eV (III) was a sub-oxide state and the fourth at 103.24 eV (IV) was from SiO2 at Si-QDs surface. With an increase in exposure to soft X-ray photons, the intensity ratio of the two peaks within the Si2p region A and B increased from 0.5 to 1.4 while the peak A intensity decreased, and eventually a steady state was reached. This observation is explained in terms of photon-induced oxidation taking place within the surface dangling bonds. As the PL profile for Si-QDs is influenced by the degree of oxidation within the nanocrystal structure, the inducement of oxidation by soft X-rays will play a role in the range of potential applications where such materials could be used - especially within biomedical labelling. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim},
  author       = {Chao, Yimin and Wang, Qi and Pietzsch, Annette and Hennies, Franz and Ni, Hongjun},
  issn         = {1862-6300},
  keyword      = {core levels,quantum dots,silicon,XPS},
  language     = {eng},
  number       = {10},
  pages        = {2424--2429},
  publisher    = {Wiley-Blackwell},
  series       = {Physica Status Solidi. A: Applications and Materials Science},
  title        = {Soft X-ray induced oxidation on acrylic acid grafted luminescent silicon quantum dots in ultrahigh vacuum},
  url          = {http://dx.doi.org/10.1002/pssa.201127212},
  volume       = {208},
  year         = {2011},
}