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Structural and spectroscopic characterization of tetranuclear iron complexes containing a (P2N2Ph)-N-R bridge

Karnahl, Michael ; Orthaber, Andreas ; Tschierlei, Stefanie ; Loganathan, Nagarajan LU and Ott, Sascha (2012) In Journal of Coordination Chemistry 65(15). p.2713-2723
Abstract
A pair of tetranuclear iron complexes consisting of two Fe-2(Cl(2)bdt)(CO)(5) subunits (Cl(2)bdt = 3,6-dicholorobenzene-1,2-dithiolate) bridged by different cyclic 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands were prepared and structurally characterized. In the solid state, the P2N2 ligands adopt a boat conformation, which results in rather short distances between the two Fe-2(Cl(2)bdt)(CO)(5) clusters that promotes electronic communication across the diphosphine ligand.
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Tetranuclear complexes, Iron carbonyl clusters, Hydrogenase models, X-ray crystallography, P2N2-ligands
in
Journal of Coordination Chemistry
volume
65
issue
15
pages
2713 - 2723
publisher
Taylor & Francis
external identifiers
  • wos:000305759500011
  • scopus:84863602121
ISSN
1026-7441
DOI
10.1080/00958972.2012.701008
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
235f2a0b-8be4-4b2e-9e6e-0ecdc78032bb (old id 2883754)
date added to LUP
2016-04-01 10:28:26
date last changed
2022-02-17 18:29:52
@article{235f2a0b-8be4-4b2e-9e6e-0ecdc78032bb,
  abstract     = {{A pair of tetranuclear iron complexes consisting of two Fe-2(Cl(2)bdt)(CO)(5) subunits (Cl(2)bdt = 3,6-dicholorobenzene-1,2-dithiolate) bridged by different cyclic 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands were prepared and structurally characterized. In the solid state, the P2N2 ligands adopt a boat conformation, which results in rather short distances between the two Fe-2(Cl(2)bdt)(CO)(5) clusters that promotes electronic communication across the diphosphine ligand.}},
  author       = {{Karnahl, Michael and Orthaber, Andreas and Tschierlei, Stefanie and Loganathan, Nagarajan and Ott, Sascha}},
  issn         = {{1026-7441}},
  keywords     = {{Tetranuclear complexes; Iron carbonyl clusters; Hydrogenase models; X-ray crystallography; P2N2-ligands}},
  language     = {{eng}},
  number       = {{15}},
  pages        = {{2713--2723}},
  publisher    = {{Taylor & Francis}},
  series       = {{Journal of Coordination Chemistry}},
  title        = {{Structural and spectroscopic characterization of tetranuclear iron complexes containing a (P2N2Ph)-N-R bridge}},
  url          = {{http://dx.doi.org/10.1080/00958972.2012.701008}},
  doi          = {{10.1080/00958972.2012.701008}},
  volume       = {{65}},
  year         = {{2012}},
}