Advanced

The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole]

Kostakis, George; Xydias, Pantelis; Nordlander, Ebbe LU and Plakatouras, John C. (2012) In Inorganica Chimica Acta 383. p.327-331
Abstract
The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]center dot 2CH(3)CN (1.2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV-Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar. (C) 2011 Elsevier B. V. All rights reserved.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Copper, 3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2, [1-(4-((1H-benzo[d][1, 3]triazole], Complex, X-ray
in
Inorganica Chimica Acta
volume
383
pages
327 - 331
publisher
Elsevier
external identifiers
  • wos:000300623600049
  • scopus:84857234259
ISSN
0020-1693
DOI
10.1016/j.ica.2011.10.063
language
English
LU publication?
yes
id
779fb62d-3dfe-49e3-a481-c40eaf953821 (old id 2390712)
date added to LUP
2012-03-29 08:25:08
date last changed
2017-05-28 04:10:07
@article{779fb62d-3dfe-49e3-a481-c40eaf953821,
  abstract     = {The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]center dot 2CH(3)CN (1.2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV-Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar. (C) 2011 Elsevier B. V. All rights reserved.},
  author       = {Kostakis, George and Xydias, Pantelis and Nordlander, Ebbe and Plakatouras, John C.},
  issn         = {0020-1693},
  keyword      = {Copper,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,[1-(4-((1H-benzo[d][1,3]triazole],Complex,X-ray},
  language     = {eng},
  pages        = {327--331},
  publisher    = {Elsevier},
  series       = {Inorganica Chimica Acta},
  title        = {The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole]},
  url          = {http://dx.doi.org/10.1016/j.ica.2011.10.063},
  volume       = {383},
  year         = {2012},
}