A tale of two mechanisms : comparing mesostructure formation in cationic and non-ionic surfactant-templated silicas
(2007) In Studies in Surface Science and Catalysis 170(B). p.1763-1769- Abstract
The formation of surfactant templated silica films at the air-solution interface has been investigated in situ using a number of time-resolved surface-sensitive and bulk sensitive techniques. Results from templating solutions prepared using a non-ionic surfactant (C16EO8) are compared to those obtained when a cationic surfactant (CTAB) is used. In both cases specific solution phase interactions drive mesostructure organisation, in the precipitates formed in the subphase and in the thin films at the solution surface, however the templating interaction between silica and surfactant appears to occur differently in each case.
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- author
- Edler, K. J. LU ; Fernandez-Martin, C. ; Brennan, T. and Roser, S. J.
- publishing date
- 2007
- type
- Chapter in Book/Report/Conference proceeding
- publication status
- published
- host publication
- From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference
- series title
- Studies in Surface Science and Catalysis
- editor
- Xu, Ruren ; Gao, Zi ; Chen, Jiesheng and Yan, Wenfu
- volume
- 170
- issue
- B
- edition
- B
- pages
- 7 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:35348883614
- ISSN
- 0167-2991
- ISBN
- 0444530681
- 9780444530684
- DOI
- 10.1016/S0167-2991(07)81057-3
- language
- English
- LU publication?
- no
- id
- 2437b6dd-cb3c-4382-bd5e-cf7e08805cff
- date added to LUP
- 2023-05-04 18:54:17
- date last changed
- 2023-06-13 08:53:04
@inbook{2437b6dd-cb3c-4382-bd5e-cf7e08805cff, abstract = {{<p>The formation of surfactant templated silica films at the air-solution interface has been investigated in situ using a number of time-resolved surface-sensitive and bulk sensitive techniques. Results from templating solutions prepared using a non-ionic surfactant (C<sub>16</sub>EO<sub>8</sub>) are compared to those obtained when a cationic surfactant (CTAB) is used. In both cases specific solution phase interactions drive mesostructure organisation, in the precipitates formed in the subphase and in the thin films at the solution surface, however the templating interaction between silica and surfactant appears to occur differently in each case.</p>}}, author = {{Edler, K. J. and Fernandez-Martin, C. and Brennan, T. and Roser, S. J.}}, booktitle = {{From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference}}, editor = {{Xu, Ruren and Gao, Zi and Chen, Jiesheng and Yan, Wenfu}}, isbn = {{0444530681}}, issn = {{0167-2991}}, language = {{eng}}, number = {{B}}, pages = {{1763--1769}}, publisher = {{Elsevier}}, series = {{Studies in Surface Science and Catalysis}}, title = {{A tale of two mechanisms : comparing mesostructure formation in cationic and non-ionic surfactant-templated silicas}}, url = {{http://dx.doi.org/10.1016/S0167-2991(07)81057-3}}, doi = {{10.1016/S0167-2991(07)81057-3}}, volume = {{170}}, year = {{2007}}, }