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Activation Parameters and Mechanism for Water Exchange of Tetraaquaplatinum(II) Studied by High-Pressure Oxygen-17 NMR Spectroscopy

Helm, Lothar; Elding, Lars Ivar LU and Merbach, Andre E. (1985) In Inorganic Chemistry 24(11). p.1719-1721
Abstract
Water exchange of tetraaquaplatinum(II) has been studies by use of high-pressure oxygen-17 NMR spectroscopy. Negative entropies and negative volumes of activation support associative activation. The tretraaquapalladium(II) complex reacts 1.4x10exp6 times faster than the corresponding platinum(II) complex.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
TetraaquaplatinumII), Water exchange, High-Pressure NMR, Oxygen-17 NMR, Activation volume, Associative reaction, Reaction mechanism, Tetraaquaplatinum(II), Water exchenge, Oxygen-17 NMR, High-pressure NMR, Reaction mechanism, Activation parameters, Associative reaction
in
Inorganic Chemistry
volume
24
issue
11
pages
3 pages
publisher
The American Chemical Society
external identifiers
  • scopus:0001221280
ISSN
1520-510X
DOI
10.1021/ic00205a026
language
English
LU publication?
yes
id
245fec3b-c446-43ec-862a-aaa794bac55c
date added to LUP
2017-02-07 20:18:36
date last changed
2017-08-27 06:34:58
@article{245fec3b-c446-43ec-862a-aaa794bac55c,
  abstract     = {Water exchange of tetraaquaplatinum(II) has been studies by use of high-pressure oxygen-17 NMR spectroscopy. Negative entropies and negative volumes of activation support associative activation. The tretraaquapalladium(II) complex reacts 1.4x10exp6 times faster than the corresponding platinum(II) complex.},
  author       = {Helm, Lothar and Elding, Lars Ivar and Merbach, Andre E.},
  issn         = {1520-510X},
  keyword      = {TetraaquaplatinumII),Water exchange,High-Pressure NMR,Oxygen-17 NMR,Activation volume,Associative reaction,Reaction mechanism,Tetraaquaplatinum(II),Water exchenge,Oxygen-17 NMR,High-pressure NMR,Reaction mechanism,Activation parameters,Associative reaction},
  language     = {eng},
  month        = {05},
  number       = {11},
  pages        = {1719--1721},
  publisher    = {The American Chemical Society},
  series       = {Inorganic Chemistry},
  title        = {Activation Parameters and Mechanism for Water Exchange of Tetraaquaplatinum(II) Studied by High-Pressure Oxygen-17 NMR Spectroscopy},
  url          = {http://dx.doi.org/10.1021/ic00205a026},
  volume       = {24},
  year         = {1985},
}