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Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands

Behrens, A; Behrens, U; Nordlander, Ebbe LU ; Bader, C and Rehder, D (2005) In Inorganica Chimica Acta 358(6). p.1970-1974
Abstract
Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17){MoO}(8)center dot 10thf center dot hexane, where {MoO}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [{(MoO)-O-IV(S'(2))} {(MoO)-O-V(S'(2))}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
molybdopterin, molybdenum complexes, thiofunctional ligands, oxotransferases
in
Inorganica Chimica Acta
volume
358
issue
6
pages
1970 - 1974
publisher
Elsevier
external identifiers
  • wos:000227975700028
  • scopus:14844298767
ISSN
0020-1693
DOI
10.1016/j.ica.2004.12.039
language
English
LU publication?
yes
id
3cf87e5d-c9b2-4358-b7b5-11eab2ac472b (old id 247090)
date added to LUP
2007-08-20 15:43:58
date last changed
2017-01-01 06:58:24
@article{3cf87e5d-c9b2-4358-b7b5-11eab2ac472b,
  abstract     = {Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17){MoO}(8)center dot 10thf center dot hexane, where {MoO}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [{(MoO)-O-IV(S'(2))} {(MoO)-O-V(S'(2))}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.},
  author       = {Behrens, A and Behrens, U and Nordlander, Ebbe and Bader, C and Rehder, D},
  issn         = {0020-1693},
  keyword      = {molybdopterin,molybdenum complexes,thiofunctional ligands,oxotransferases},
  language     = {eng},
  number       = {6},
  pages        = {1970--1974},
  publisher    = {Elsevier},
  series       = {Inorganica Chimica Acta},
  title        = {Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands},
  url          = {http://dx.doi.org/10.1016/j.ica.2004.12.039},
  volume       = {358},
  year         = {2005},
}