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Synthesis of a Ru(bpy)(3)-type complex linked to a free terpyridine ligand and its use for preparation of polynuclear bimetallic complexes

Wolpher, H ; Huang, Ping LU ; Borgstrom, M ; Bergquist, J ; Styring, Stenbjörn LU ; Sun, LC and Akermark, B (2004) In Catalysis Today 98(4). p.529-536
Abstract
A terpyridine ligand has been covalently linked to a Ru(bpy)(3) complex via an amide bond. By using this functionalized terpyridine ligand, a series of multinuclear bimetallic complexes have been synthesized and characterized. One of these complexes has the structure of di-mu-oxobridged Mn dimer. EPR spectra of this complex showed that, depending on the procedure for the preparation, the oxidation states of the Mn dimer is either a Mn-2(III,IV) dimer or a mixture of this and Mn-2(IV,IV) dimer. Water oxidation catalyzed by this complex has been performed.
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
electrochemistry, ruthenium-manganese, photosystem II, water oxidation, artificial photosynthesis, EPR, homogeneous catalysis
in
Catalysis Today
volume
98
issue
4
pages
529 - 536
publisher
Elsevier
external identifiers
  • wos:000225911300011
  • scopus:10044261198
ISSN
0920-5861
DOI
10.1016/j.cattod.2004.09.008
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Center for Chemistry and Chemical Engineering (011001000), Biochemistry and Structural Biology (S) (000006142)
id
ea4d34f3-1816-4e49-bc84-7375da71a9d6 (old id 259028)
date added to LUP
2016-04-01 15:25:04
date last changed
2022-01-28 05:16:08
@article{ea4d34f3-1816-4e49-bc84-7375da71a9d6,
  abstract     = {{A terpyridine ligand has been covalently linked to a Ru(bpy)(3) complex via an amide bond. By using this functionalized terpyridine ligand, a series of multinuclear bimetallic complexes have been synthesized and characterized. One of these complexes has the structure of di-mu-oxobridged Mn dimer. EPR spectra of this complex showed that, depending on the procedure for the preparation, the oxidation states of the Mn dimer is either a Mn-2(III,IV) dimer or a mixture of this and Mn-2(IV,IV) dimer. Water oxidation catalyzed by this complex has been performed.}},
  author       = {{Wolpher, H and Huang, Ping and Borgstrom, M and Bergquist, J and Styring, Stenbjörn and Sun, LC and Akermark, B}},
  issn         = {{0920-5861}},
  keywords     = {{electrochemistry; ruthenium-manganese; photosystem II; water oxidation; artificial photosynthesis; EPR; homogeneous catalysis}},
  language     = {{eng}},
  number       = {{4}},
  pages        = {{529--536}},
  publisher    = {{Elsevier}},
  series       = {{Catalysis Today}},
  title        = {{Synthesis of a Ru(bpy)(3)-type complex linked to a free terpyridine ligand and its use for preparation of polynuclear bimetallic complexes}},
  url          = {{http://dx.doi.org/10.1016/j.cattod.2004.09.008}},
  doi          = {{10.1016/j.cattod.2004.09.008}},
  volume       = {{98}},
  year         = {{2004}},
}