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Solvent-free synthesis of chiral molecularly imprinted polymers: Porosity control using a nano-sized solid porogen

Duarte, Mariana LU ; Billing, Johan and Yilmaz, Ecevit (2016) In Journal of Applied Polymer Science 133(41). p.44104-44104
Abstract
Molecularly imprinted polymers (MIPs) have been synthesized in the absence of a solvent using fumed silica nanoparticles to create a porous network. The method employed led to a chiral imprinting effect and allowed for an excellent control over the internal morphology of imprinted and non-imprinted polymer (NIP) materials. The polymers possess high surface areas (>300 m2) and identical pore size (112 Å). The MIP exhibited an imprinting factor (IF) of 9 and a selectivity value (α) of 1.83 for (−)-ephedrine.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Applied Polymer Science
volume
133
issue
41
pages
5 pages
publisher
John Wiley & Sons
external identifiers
  • scopus:84978926964
  • wos:000380728200027
ISSN
1097-4628
DOI
10.1002/app.44104
language
English
LU publication?
yes
id
26bafbd1-84e6-498d-b57e-2b817a10c8a5
date added to LUP
2016-09-21 11:45:31
date last changed
2017-10-22 05:19:25
@article{26bafbd1-84e6-498d-b57e-2b817a10c8a5,
  abstract     = {Molecularly imprinted polymers (MIPs) have been synthesized in the absence of a solvent using fumed silica nanoparticles to create a porous network. The method employed led to a chiral imprinting effect and allowed for an excellent control over the internal morphology of imprinted and non-imprinted polymer (NIP) materials. The polymers possess high surface areas (>300 m2) and identical pore size (112 Å). The MIP exhibited an imprinting factor (IF) of 9 and a selectivity value (α) of 1.83 for (−)-ephedrine. },
  author       = {Duarte, Mariana and Billing, Johan and Yilmaz, Ecevit},
  issn         = {1097-4628},
  language     = {eng},
  month        = {07},
  number       = {41},
  pages        = {44104--44104},
  publisher    = {John Wiley & Sons},
  series       = {Journal of Applied Polymer Science},
  title        = {Solvent-free synthesis of chiral molecularly imprinted polymers: Porosity control using a nano-sized solid porogen},
  url          = {http://dx.doi.org/10.1002/app.44104},
  volume       = {133},
  year         = {2016},
}