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Lifetime and predissociation yield of N-14(2) b (1)Pi(u)(v=1)

Sprengers, JP; Johansson, Allan LU ; Ubachs, W; L'Huillier, Anne LU ; Wahlström, Claes-Göran LU ; Lang, R; Lewis, BR and Gibson, ST (2004) In Journal of Chemical Physics 120(19). p.8973-8978
Abstract
The lifetime of the b (1)Pi(u)(v=1) state in N-14(2) has been determined experimentally using a laser-based pump-probe scheme and an exceptionally long lifetime of 2.61 ns was found. Semiempirical close-coupling calculations of the radiative lifetime, which include Rydberg-valence interactions in the singlet manifold, are consistent with this large value, giving a value of 3.61 ns and suggesting a predissociation yield of similar to28% for this level of the b state. (C) 2004 American Institute of Physics.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Chemical Physics
volume
120
issue
19
pages
8973 - 8978
publisher
American Institute of Physics
external identifiers
  • wos:000221146400010
  • scopus:2942568207
ISSN
0021-9606
DOI
10.1063/1.1704640
language
English
LU publication?
yes
id
0624aa6e-64a1-40e8-9dd0-847c00758f5c (old id 279757)
date added to LUP
2007-11-02 08:42:45
date last changed
2017-01-01 04:46:34
@article{0624aa6e-64a1-40e8-9dd0-847c00758f5c,
  abstract     = {The lifetime of the b (1)Pi(u)(v=1) state in N-14(2) has been determined experimentally using a laser-based pump-probe scheme and an exceptionally long lifetime of 2.61 ns was found. Semiempirical close-coupling calculations of the radiative lifetime, which include Rydberg-valence interactions in the singlet manifold, are consistent with this large value, giving a value of 3.61 ns and suggesting a predissociation yield of similar to28% for this level of the b state. (C) 2004 American Institute of Physics.},
  author       = {Sprengers, JP and Johansson, Allan and Ubachs, W and L'Huillier, Anne and Wahlström, Claes-Göran and Lang, R and Lewis, BR and Gibson, ST},
  issn         = {0021-9606},
  language     = {eng},
  number       = {19},
  pages        = {8973--8978},
  publisher    = {American Institute of Physics},
  series       = {Journal of Chemical Physics},
  title        = {Lifetime and predissociation yield of N-14(2) b (1)Pi(u)(v=1)},
  url          = {http://dx.doi.org/10.1063/1.1704640},
  volume       = {120},
  year         = {2004},
}