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Molecular nature of resonant x-ray scattering in solid LiNO3

Preobrajenski, Alexei LU ; Vinogradov, AS; Krasnikov, SA; Szargan, R and Mårtensson, Nils LU (2004) In Physical Review B (Condensed Matter and Materials Physics) 69(11).
Abstract
Resonant x-ray emission spectroscopy has been applied to study radiative decay processes following the N 1s near-edge excitations in solid LiNO3. It has been shown that the origin of both nonresonant and resonant spectra are essentially molecular, their shape being primarily determined by the electron transitions between molecular orbitals of the quasiisolated NO3- anion. A strong low-energy sideband observed in the recombination spectrum following the N 1s(-1)pi(*) excitation is attributed to the effect of dynamical x-ray emission accompanying the D-3h-->C-3v distortion of the core-excited NO3- species.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Physical Review B (Condensed Matter and Materials Physics)
volume
69
issue
11
publisher
American Physical Society
external identifiers
  • wos:000220814000053
  • scopus:2142651456
ISSN
1098-0121
DOI
10.1103/PhysRevB.69.115116
language
English
LU publication?
yes
id
5693aa2e-d261-4665-a6ef-d314104a1e11 (old id 281748)
date added to LUP
2007-10-30 07:41:15
date last changed
2017-10-01 04:40:30
@article{5693aa2e-d261-4665-a6ef-d314104a1e11,
  abstract     = {Resonant x-ray emission spectroscopy has been applied to study radiative decay processes following the N 1s near-edge excitations in solid LiNO3. It has been shown that the origin of both nonresonant and resonant spectra are essentially molecular, their shape being primarily determined by the electron transitions between molecular orbitals of the quasiisolated NO3- anion. A strong low-energy sideband observed in the recombination spectrum following the N 1s(-1)pi(*) excitation is attributed to the effect of dynamical x-ray emission accompanying the D-3h-->C-3v distortion of the core-excited NO3- species.},
  author       = {Preobrajenski, Alexei and Vinogradov, AS and Krasnikov, SA and Szargan, R and Mårtensson, Nils},
  issn         = {1098-0121},
  language     = {eng},
  number       = {11},
  publisher    = {American Physical Society},
  series       = {Physical Review B (Condensed Matter and Materials Physics)},
  title        = {Molecular nature of resonant x-ray scattering in solid LiNO3},
  url          = {http://dx.doi.org/10.1103/PhysRevB.69.115116},
  volume       = {69},
  year         = {2004},
}