Molecular nature of resonant x-ray scattering in solid LiNO3
(2004) In Physical Review B (Condensed Matter and Materials Physics) 69(11).- Abstract
- Resonant x-ray emission spectroscopy has been applied to study radiative decay processes following the N 1s near-edge excitations in solid LiNO3. It has been shown that the origin of both nonresonant and resonant spectra are essentially molecular, their shape being primarily determined by the electron transitions between molecular orbitals of the quasiisolated NO3- anion. A strong low-energy sideband observed in the recombination spectrum following the N 1s(-1)pi(*) excitation is attributed to the effect of dynamical x-ray emission accompanying the D-3h-->C-3v distortion of the core-excited NO3- species.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/281748
- author
- Preobrajenski, Alexei LU ; Vinogradov, AS ; Krasnikov, SA ; Szargan, R and Mårtensson, Nils LU
- organization
- publishing date
- 2004
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Physical Review B (Condensed Matter and Materials Physics)
- volume
- 69
- issue
- 11
- publisher
- American Physical Society
- external identifiers
-
- wos:000220814000053
- scopus:2142651456
- ISSN
- 1098-0121
- DOI
- 10.1103/PhysRevB.69.115116
- language
- English
- LU publication?
- yes
- id
- 5693aa2e-d261-4665-a6ef-d314104a1e11 (old id 281748)
- date added to LUP
- 2016-04-01 16:03:41
- date last changed
- 2022-01-28 17:00:48
@article{5693aa2e-d261-4665-a6ef-d314104a1e11, abstract = {{Resonant x-ray emission spectroscopy has been applied to study radiative decay processes following the N 1s near-edge excitations in solid LiNO3. It has been shown that the origin of both nonresonant and resonant spectra are essentially molecular, their shape being primarily determined by the electron transitions between molecular orbitals of the quasiisolated NO3- anion. A strong low-energy sideband observed in the recombination spectrum following the N 1s(-1)pi(*) excitation is attributed to the effect of dynamical x-ray emission accompanying the D-3h-->C-3v distortion of the core-excited NO3- species.}}, author = {{Preobrajenski, Alexei and Vinogradov, AS and Krasnikov, SA and Szargan, R and Mårtensson, Nils}}, issn = {{1098-0121}}, language = {{eng}}, number = {{11}}, publisher = {{American Physical Society}}, series = {{Physical Review B (Condensed Matter and Materials Physics)}}, title = {{Molecular nature of resonant x-ray scattering in solid LiNO3}}, url = {{http://dx.doi.org/10.1103/PhysRevB.69.115116}}, doi = {{10.1103/PhysRevB.69.115116}}, volume = {{69}}, year = {{2004}}, }