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Structural and spectroscopic characterization of tetranuclear iron complexes containing a (P2N2Ph)-N-R bridge

Karnahl, Michael; Orthaber, Andreas; Tschierlei, Stefanie; Loganathan, Nagarajan LU and Ott, Sascha (2012) In Journal of Coordination Chemistry 65(15). p.2713-2723
Abstract
A pair of tetranuclear iron complexes consisting of two Fe-2(Cl(2)bdt)(CO)(5) subunits (Cl(2)bdt = 3,6-dicholorobenzene-1,2-dithiolate) bridged by different cyclic 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands were prepared and structurally characterized. In the solid state, the P2N2 ligands adopt a boat conformation, which results in rather short distances between the two Fe-2(Cl(2)bdt)(CO)(5) clusters that promotes electronic communication across the diphosphine ligand.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Tetranuclear complexes, Iron carbonyl clusters, Hydrogenase models, X-ray crystallography, P2N2-ligands
in
Journal of Coordination Chemistry
volume
65
issue
15
pages
2713 - 2723
publisher
Taylor & Francis
external identifiers
  • wos:000305759500011
  • scopus:84863602121
ISSN
1026-7441
DOI
10.1080/00958972.2012.701008
language
English
LU publication?
yes
id
235f2a0b-8be4-4b2e-9e6e-0ecdc78032bb (old id 2883754)
date added to LUP
2012-07-24 15:57:21
date last changed
2017-01-01 03:37:32
@article{235f2a0b-8be4-4b2e-9e6e-0ecdc78032bb,
  abstract     = {A pair of tetranuclear iron complexes consisting of two Fe-2(Cl(2)bdt)(CO)(5) subunits (Cl(2)bdt = 3,6-dicholorobenzene-1,2-dithiolate) bridged by different cyclic 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands were prepared and structurally characterized. In the solid state, the P2N2 ligands adopt a boat conformation, which results in rather short distances between the two Fe-2(Cl(2)bdt)(CO)(5) clusters that promotes electronic communication across the diphosphine ligand.},
  author       = {Karnahl, Michael and Orthaber, Andreas and Tschierlei, Stefanie and Loganathan, Nagarajan and Ott, Sascha},
  issn         = {1026-7441},
  keyword      = {Tetranuclear complexes,Iron carbonyl clusters,Hydrogenase models,X-ray crystallography,P2N2-ligands},
  language     = {eng},
  number       = {15},
  pages        = {2713--2723},
  publisher    = {Taylor & Francis},
  series       = {Journal of Coordination Chemistry},
  title        = {Structural and spectroscopic characterization of tetranuclear iron complexes containing a (P2N2Ph)-N-R bridge},
  url          = {http://dx.doi.org/10.1080/00958972.2012.701008},
  volume       = {65},
  year         = {2012},
}