Structural and spectroscopic characterization of tetranuclear iron complexes containing a (P2N2Ph)-N-R bridge
(2012) In Journal of Coordination Chemistry 65(15). p.2713-2723- Abstract
- A pair of tetranuclear iron complexes consisting of two Fe-2(Cl(2)bdt)(CO)(5) subunits (Cl(2)bdt = 3,6-dicholorobenzene-1,2-dithiolate) bridged by different cyclic 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands were prepared and structurally characterized. In the solid state, the P2N2 ligands adopt a boat conformation, which results in rather short distances between the two Fe-2(Cl(2)bdt)(CO)(5) clusters that promotes electronic communication across the diphosphine ligand.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2883754
- author
- Karnahl, Michael ; Orthaber, Andreas ; Tschierlei, Stefanie ; Loganathan, Nagarajan LU and Ott, Sascha
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Tetranuclear complexes, Iron carbonyl clusters, Hydrogenase models, X-ray crystallography, P2N2-ligands
- in
- Journal of Coordination Chemistry
- volume
- 65
- issue
- 15
- pages
- 2713 - 2723
- publisher
- Taylor & Francis
- external identifiers
-
- wos:000305759500011
- scopus:84863602121
- ISSN
- 1026-7441
- DOI
- 10.1080/00958972.2012.701008
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- 235f2a0b-8be4-4b2e-9e6e-0ecdc78032bb (old id 2883754)
- date added to LUP
- 2016-04-01 10:28:26
- date last changed
- 2022-02-17 18:29:52
@article{235f2a0b-8be4-4b2e-9e6e-0ecdc78032bb, abstract = {{A pair of tetranuclear iron complexes consisting of two Fe-2(Cl(2)bdt)(CO)(5) subunits (Cl(2)bdt = 3,6-dicholorobenzene-1,2-dithiolate) bridged by different cyclic 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands were prepared and structurally characterized. In the solid state, the P2N2 ligands adopt a boat conformation, which results in rather short distances between the two Fe-2(Cl(2)bdt)(CO)(5) clusters that promotes electronic communication across the diphosphine ligand.}}, author = {{Karnahl, Michael and Orthaber, Andreas and Tschierlei, Stefanie and Loganathan, Nagarajan and Ott, Sascha}}, issn = {{1026-7441}}, keywords = {{Tetranuclear complexes; Iron carbonyl clusters; Hydrogenase models; X-ray crystallography; P2N2-ligands}}, language = {{eng}}, number = {{15}}, pages = {{2713--2723}}, publisher = {{Taylor & Francis}}, series = {{Journal of Coordination Chemistry}}, title = {{Structural and spectroscopic characterization of tetranuclear iron complexes containing a (P2N2Ph)-N-R bridge}}, url = {{http://dx.doi.org/10.1080/00958972.2012.701008}}, doi = {{10.1080/00958972.2012.701008}}, volume = {{65}}, year = {{2012}}, }