A quantitative analysis of the N 1s ->pi* photoabsorption profile in N-2: new spectroscopical constants for the core-excited state
(2004) In Chemical Physics Letters 383(3-4). p.222-229- Abstract
- The N 1s --> pi* photoabsorption profile of N-2 is quantitatively analysed. New spectroscopical constants for the N 1s(-1) pi* core-excited state are determined from NEXAFS spectra and compared to previously published data. The accuracy of the new spectroscopical constants is discussed and error bars are given for the present data analysis. The goodness of the new spectroscopical constants is demonstrated by lifetime vibrational interference (LVI) simulations of the resonant Auger decay from the N 1s(-1) pi* core-excited state to the A(2)Pi(u) singly ionized final state of N-2. These new values give a much better agreement with recently obtained experimental data compared to the previously published ones.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/290858
- author
- Feifel, R ; Andersson, M ; Ohrwall, G ; Ristinmaa Sörensen, Stacey LU ; Piancastelli, MN ; Tchaplyguine, M ; Bjorneholm, O ; Karlsson, L and Svensson, S
- organization
- publishing date
- 2004
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Physics Letters
- volume
- 383
- issue
- 3-4
- pages
- 222 - 229
- publisher
- Elsevier
- external identifiers
-
- wos:000187956600002
- scopus:1642524219
- ISSN
- 0009-2614
- DOI
- 10.1016/j.cplett.2003.11.026
- language
- English
- LU publication?
- yes
- id
- a08e2766-7588-4905-92f1-6410a95a44f0 (old id 290858)
- date added to LUP
- 2016-04-01 16:53:19
- date last changed
- 2024-01-11 16:45:57
@article{a08e2766-7588-4905-92f1-6410a95a44f0, abstract = {{The N 1s --> pi* photoabsorption profile of N-2 is quantitatively analysed. New spectroscopical constants for the N 1s(-1) pi* core-excited state are determined from NEXAFS spectra and compared to previously published data. The accuracy of the new spectroscopical constants is discussed and error bars are given for the present data analysis. The goodness of the new spectroscopical constants is demonstrated by lifetime vibrational interference (LVI) simulations of the resonant Auger decay from the N 1s(-1) pi* core-excited state to the A(2)Pi(u) singly ionized final state of N-2. These new values give a much better agreement with recently obtained experimental data compared to the previously published ones.}}, author = {{Feifel, R and Andersson, M and Ohrwall, G and Ristinmaa Sörensen, Stacey and Piancastelli, MN and Tchaplyguine, M and Bjorneholm, O and Karlsson, L and Svensson, S}}, issn = {{0009-2614}}, language = {{eng}}, number = {{3-4}}, pages = {{222--229}}, publisher = {{Elsevier}}, series = {{Chemical Physics Letters}}, title = {{A quantitative analysis of the N 1s ->pi* photoabsorption profile in N-2: new spectroscopical constants for the core-excited state}}, url = {{http://dx.doi.org/10.1016/j.cplett.2003.11.026}}, doi = {{10.1016/j.cplett.2003.11.026}}, volume = {{383}}, year = {{2004}}, }