Activating 2D MoS2 by loading 2D Cu–S nanoplatelets for improved visible light photocatalytic hydrogen evolution, drug degradation, and CO2 reduction
Temerov, Filipp ; Greco, Rossella ; Celis, Joran ; Eslava, Salvador ; Wang, Weimin LU
; Yamamoto, Takashi
and Cao, Wei
(2024)
In Results in Materials
22.
- Abstract
Finding reliable photocatalysts capable of driving reactions using only sunlight is more needed than ever. A variety of strategies to harvest sunlight and convert it into chemical energy have been successfully utilized such as synthesizing nanostructures, using metal nanoparticles, doping, and others. In this work, we discover a facile way to anchor CuS nanoplatelets on 2D MoS2 by the solvothermal method using ethylene glycol (EG) as both a reduction agent and an exfoliating agent of bulk MoS2. Using CuS as a co-catalysis on MoS2 with their huge surface areas, led to improved photocatalytic activity for three different applications including H2 evolution, CO2 reduction, and... (More)
Finding reliable photocatalysts capable of driving reactions using only sunlight is more needed than ever. A variety of strategies to harvest sunlight and convert it into chemical energy have been successfully utilized such as synthesizing nanostructures, using metal nanoparticles, doping, and others. In this work, we discover a facile way to anchor CuS nanoplatelets on 2D MoS2 by the solvothermal method using ethylene glycol (EG) as both a reduction agent and an exfoliating agent of bulk MoS2. Using CuS as a co-catalysis on MoS2 with their huge surface areas, led to improved photocatalytic activity for three different applications including H2 evolution, CO2 reduction, and endosulfan degradation. Specifically, Cu–S@MoS2 3% nanocomposite produced 9.86 μmol g−1 h−1 of H2, 0.48 μmol g−1 h−1 of CO and full decomposition of endosulfan within 6 h. The Cu-loaded MoS2 nanocomposites were thoroughly characterized by spectroscopic (including synchrotron-based spectroscopy) and microscopic methods to understand the formation of Cu–S during the solvothermal process. Moreover, the role of the EG during the synthetic procedure was revealed experimentally and studied theoretically via DFT simulations.
(Less)
- author
- Temerov, Filipp
; Greco, Rossella
; Celis, Joran
; Eslava, Salvador
; Wang, Weimin
LU
; Yamamoto, Takashi
and Cao, Wei
- organization
- publishing date
- 2024-06
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Results in Materials
- volume
- 22
- article number
- 100569
- publisher
- Elsevier
- external identifiers
-
- scopus:85189835375
- ISSN
- 2590-048X
- DOI
- 10.1016/j.rinma.2024.100569
- language
- English
- LU publication?
- yes
- id
- 29a66c2a-13e7-47e0-b9e6-57f613601eb1
- date added to LUP
- 2024-04-23 10:11:07
- date last changed
- 2024-04-24 10:32:13
@article{29a66c2a-13e7-47e0-b9e6-57f613601eb1,
abstract = {{<p>Finding reliable photocatalysts capable of driving reactions using only sunlight is more needed than ever. A variety of strategies to harvest sunlight and convert it into chemical energy have been successfully utilized such as synthesizing nanostructures, using metal nanoparticles, doping, and others. In this work, we discover a facile way to anchor CuS nanoplatelets on 2D MoS<sub>2</sub> by the solvothermal method using ethylene glycol (EG) as both a reduction agent and an exfoliating agent of bulk MoS<sub>2</sub>. Using CuS as a co-catalysis on MoS<sub>2</sub> with their huge surface areas, led to improved photocatalytic activity for three different applications including H<sub>2</sub> evolution, CO<sub>2</sub> reduction, and endosulfan degradation. Specifically, Cu–S@MoS<sub>2</sub> 3% nanocomposite produced 9.86 μmol g<sup>−1</sup> h<sup>−1</sup> of H<sub>2</sub>, 0.48 μmol g<sup>−1</sup> h<sup>−1</sup> of CO and full decomposition of endosulfan within 6 h. The Cu-loaded MoS<sub>2</sub> nanocomposites were thoroughly characterized by spectroscopic (including synchrotron-based spectroscopy) and microscopic methods to understand the formation of Cu–S during the solvothermal process. Moreover, the role of the EG during the synthetic procedure was revealed experimentally and studied theoretically via DFT simulations.</p>}},
author = {{Temerov, Filipp and Greco, Rossella and Celis, Joran and Eslava, Salvador and Wang, Weimin and Yamamoto, Takashi and Cao, Wei}},
issn = {{2590-048X}},
language = {{eng}},
publisher = {{Elsevier}},
series = {{Results in Materials}},
title = {{Activating 2D MoS<sub>2</sub> by loading 2D Cu–S nanoplatelets for improved visible light photocatalytic hydrogen evolution, drug degradation, and CO<sub>2</sub> reduction}},
url = {{http://dx.doi.org/10.1016/j.rinma.2024.100569}},
doi = {{10.1016/j.rinma.2024.100569}},
volume = {{22}},
year = {{2024}},
}