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Picosecond time-resolved X-ray emission spectroscopy : Ultrafast spin-state determination in an iron complex

Vankó, György; Glatzel, Pieter; Abela, Rafael; Grolimund, Daniel; Borca, Camelia N.; Johnson, Steven L.; Milne, Christopher J.; Bressler, Christian and Pham, Van-Thai LU (2010) In Angewandte Chemie - International Edition 49(34). p.5910-5912
Abstract

(Figure Presented) Ultrafast spin probe: A short-lived transient species of light-excited [Fe(bpy) 3 ] 2+ (bpy = 2,2′-bipyridine) shows geometry variations that correspond to excitation to a high-spin state, in which the spin momentum of Fe" has now been directly determined to be S = 2 by spin-sensitive ultrafast X-ray emission spectroscopy.

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author
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Femtochemistry, Iron, Spin crossover, Time-resolved spectroscopy, X-ray emission spectroscopy
in
Angewandte Chemie - International Edition
volume
49
issue
34
pages
3 pages
publisher
John Wiley & Sons
external identifiers
  • scopus:77955583341
ISSN
1433-7851
DOI
10.1002/anie.201000844
language
English
LU publication?
no
id
2b5bbeaf-238c-44f7-9670-f1d9fc404ffc
date added to LUP
2019-06-30 09:55:55
date last changed
2019-07-30 05:05:30
@article{2b5bbeaf-238c-44f7-9670-f1d9fc404ffc,
  abstract     = {<p>                            (Figure Presented) Ultrafast spin probe: A short-lived transient species of light-excited [Fe(bpy)                            <sub>3</sub>                            ]                            <sup>2+</sup>                             (bpy = 2,2′-bipyridine) shows geometry variations that correspond to excitation to a high-spin state, in which the spin momentum of Fe" has now been directly determined to be S = 2 by spin-sensitive ultrafast X-ray emission spectroscopy.</p>},
  author       = {Vankó, György and Glatzel, Pieter and Abela, Rafael and Grolimund, Daniel and Borca, Camelia N. and Johnson, Steven L. and Milne, Christopher J. and Bressler, Christian and Pham, Van-Thai},
  issn         = {1433-7851},
  keyword      = {Femtochemistry,Iron,Spin crossover,Time-resolved spectroscopy,X-ray emission spectroscopy},
  language     = {eng},
  month        = {08},
  number       = {34},
  pages        = {5910--5912},
  publisher    = {John Wiley & Sons},
  series       = {Angewandte Chemie - International Edition},
  title        = {Picosecond time-resolved X-ray emission spectroscopy : Ultrafast spin-state determination in an iron complex},
  url          = {http://dx.doi.org/10.1002/anie.201000844},
  volume       = {49},
  year         = {2010},
}