Picosecond time-resolved X-ray emission spectroscopy : Ultrafast spin-state determination in an iron complex
(2010) In Angewandte Chemie - International Edition 49(34). p.5910-5912- Abstract
(Figure Presented) Ultrafast spin probe: A short-lived transient species of light-excited [Fe(bpy) 3 ] 2+ (bpy = 2,2′-bipyridine) shows geometry variations that correspond to excitation to a high-spin state, in which the spin momentum of Fe" has now been directly determined to be S = 2 by spin-sensitive ultrafast X-ray emission spectroscopy.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2b5bbeaf-238c-44f7-9670-f1d9fc404ffc
- author
- Vankó, György ; Glatzel, Pieter ; Abela, Rafael ; Grolimund, Daniel ; Borca, Camelia N. ; Johnson, Steven L. ; Milne, Christopher J. ; Bressler, Christian and Pham, Van-Thai LU
- publishing date
- 2010-08-09
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Femtochemistry, Iron, Spin crossover, Time-resolved spectroscopy, X-ray emission spectroscopy
- in
- Angewandte Chemie - International Edition
- volume
- 49
- issue
- 34
- pages
- 3 pages
- publisher
- John Wiley & Sons Inc.
- external identifiers
-
- scopus:77955583341
- ISSN
- 1433-7851
- DOI
- 10.1002/anie.201000844
- language
- English
- LU publication?
- no
- id
- 2b5bbeaf-238c-44f7-9670-f1d9fc404ffc
- date added to LUP
- 2019-06-30 09:55:55
- date last changed
- 2022-03-18 02:48:39
@article{2b5bbeaf-238c-44f7-9670-f1d9fc404ffc, abstract = {{<p> (Figure Presented) Ultrafast spin probe: A short-lived transient species of light-excited [Fe(bpy) <sub>3</sub> ] <sup>2+</sup> (bpy = 2,2′-bipyridine) shows geometry variations that correspond to excitation to a high-spin state, in which the spin momentum of Fe" has now been directly determined to be S = 2 by spin-sensitive ultrafast X-ray emission spectroscopy.</p>}}, author = {{Vankó, György and Glatzel, Pieter and Abela, Rafael and Grolimund, Daniel and Borca, Camelia N. and Johnson, Steven L. and Milne, Christopher J. and Bressler, Christian and Pham, Van-Thai}}, issn = {{1433-7851}}, keywords = {{Femtochemistry; Iron; Spin crossover; Time-resolved spectroscopy; X-ray emission spectroscopy}}, language = {{eng}}, month = {{08}}, number = {{34}}, pages = {{5910--5912}}, publisher = {{John Wiley & Sons Inc.}}, series = {{Angewandte Chemie - International Edition}}, title = {{Picosecond time-resolved X-ray emission spectroscopy : Ultrafast spin-state determination in an iron complex}}, url = {{http://dx.doi.org/10.1002/anie.201000844}}, doi = {{10.1002/anie.201000844}}, volume = {{49}}, year = {{2010}}, }