Structure and Bonding of Ethylene Oxide on Si(100)
(2009) In Journal of Physical Chemistry C 113(36). p.16077-16082- Abstract
- The bonding configuration and electronic structure of ethylene oxide adsorbed on Si(100)-(2 x 1) is investigated with fully polarization resolved X-ray absorption spectroscopy as well as with core level and valence band photoemission spectroscopy. Ethylene oxide is found to adsorb via a ring-opening reaction, where the molecule forms a five-membered ring together with the silicon surface dimer atoms inserting between a carbon and the oxygen atom. In the resulting geometry, the molecule is tilted out of the surface plane.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1492327
- author
- Hennies, Franz LU ; Bao, Z. ; Travnikova, O. and Piancastelli, M. N.
- organization
- publishing date
- 2009
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Physical Chemistry C
- volume
- 113
- issue
- 36
- pages
- 16077 - 16082
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000269654700046
- scopus:70349098435
- ISSN
- 1932-7447
- DOI
- 10.1021/jp9030859
- language
- English
- LU publication?
- yes
- id
- 2bc6c5eb-de7f-4b19-957e-eb094a3843dd (old id 1492327)
- date added to LUP
- 2016-04-01 11:55:40
- date last changed
- 2022-02-25 23:24:25
@article{2bc6c5eb-de7f-4b19-957e-eb094a3843dd, abstract = {{The bonding configuration and electronic structure of ethylene oxide adsorbed on Si(100)-(2 x 1) is investigated with fully polarization resolved X-ray absorption spectroscopy as well as with core level and valence band photoemission spectroscopy. Ethylene oxide is found to adsorb via a ring-opening reaction, where the molecule forms a five-membered ring together with the silicon surface dimer atoms inserting between a carbon and the oxygen atom. In the resulting geometry, the molecule is tilted out of the surface plane.}}, author = {{Hennies, Franz and Bao, Z. and Travnikova, O. and Piancastelli, M. N.}}, issn = {{1932-7447}}, language = {{eng}}, number = {{36}}, pages = {{16077--16082}}, publisher = {{The American Chemical Society (ACS)}}, series = {{Journal of Physical Chemistry C}}, title = {{Structure and Bonding of Ethylene Oxide on Si(100)}}, url = {{http://dx.doi.org/10.1021/jp9030859}}, doi = {{10.1021/jp9030859}}, volume = {{113}}, year = {{2009}}, }