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Laccase bound to cryogel functionalized with phenylalanine for the decolorization of textile dyes

Perçin, Işik ; ARACAGÖK, Yusuf Doruk ; Idil, Neslihan ; Denizli, Adil and Mattiasson, Bo LU (2021) In Turkish Journal of Chemistry 45(5). p.1353-1365
Abstract

In this study, amino acid functionalized poly(2-hydroxyethyl methacrylate-N-methacrylolyl-l-phenylalanine) [PHEMAPA] cryogel discs were prepared. In this respect, phenylalanine containing N-methacryloyl-(L)-phenylalanine methyl ester (MAPA) was polymerized with 2-hydroxyethyl methacrylate (HEMA) without requirement of any activation step. Laccase bound poly(2-hydroxyethyl methacrylate-N-methacryloyl-l-phenylalanine) [Lac-PHEMAPA] cryogel discs were applied for decolorization of Reactive Blue-247 (RB-247). The ability of Lac-PHEMAPA cryogel discs on dye decolorization was found to be as 90% in 2 h and even more within 4h. The decolorization activities of 86% and 73% were observed at relatively low (4°C) and high (60°C) temperatures,... (More)

In this study, amino acid functionalized poly(2-hydroxyethyl methacrylate-N-methacrylolyl-l-phenylalanine) [PHEMAPA] cryogel discs were prepared. In this respect, phenylalanine containing N-methacryloyl-(L)-phenylalanine methyl ester (MAPA) was polymerized with 2-hydroxyethyl methacrylate (HEMA) without requirement of any activation step. Laccase bound poly(2-hydroxyethyl methacrylate-N-methacryloyl-l-phenylalanine) [Lac-PHEMAPA] cryogel discs were applied for decolorization of Reactive Blue-247 (RB-247). The ability of Lac-PHEMAPA cryogel discs on dye decolorization was found to be as 90% in 2 h and even more within 4h. The decolorization activities of 86% and 73% were observed at relatively low (4°C) and high (60°C) temperatures, respectively. The effect of dye concentration on dye decolorization and 100% decolorization activity was achieved in dye concentration between 50-300 ppm. Lac-PHEMAPA cryogel discs maintained 80% of its decolorization activity after six cycles. Consequently, the PHEMAPA cryogel discs are promising materials for immobilizing laccase. The Lac-PHEMAPA has a rapid dye decolorization in a broad range of temperature. The preparation is furthermore very stable and activity is preserved during storage.

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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Cryogel, Laccase, N-methacryloyl-(L)-phenylalanine methyl ester, Reactive blue, Textile dye decolorization
in
Turkish Journal of Chemistry
volume
45
issue
5
pages
13 pages
publisher
Scientific Technical Research Council Turkey-Tubitak
external identifiers
  • scopus:85117584537
  • pmid:34849053
ISSN
1300-0527
DOI
10.3906/kim-2106-16
language
English
LU publication?
yes
additional info
Publisher Copyright: © 2021 TUBITAK. All rights reserved.
id
2bce2898-5107-497d-a011-b6a4f5f3fd4d
date added to LUP
2021-11-05 11:32:07
date last changed
2024-06-01 19:18:13
@article{2bce2898-5107-497d-a011-b6a4f5f3fd4d,
  abstract     = {{<p>In this study, amino acid functionalized poly(2-hydroxyethyl methacrylate-N-methacrylolyl-l-phenylalanine) [PHEMAPA] cryogel discs were prepared. In this respect, phenylalanine containing N-methacryloyl-(L)-phenylalanine methyl ester (MAPA) was polymerized with 2-hydroxyethyl methacrylate (HEMA) without requirement of any activation step. Laccase bound poly(2-hydroxyethyl methacrylate-N-methacryloyl-l-phenylalanine) [Lac-PHEMAPA] cryogel discs were applied for decolorization of Reactive Blue-247 (RB-247). The ability of Lac-PHEMAPA cryogel discs on dye decolorization was found to be as 90% in 2 h and even more within 4h. The decolorization activities of 86% and 73% were observed at relatively low (4°C) and high (60°C) temperatures, respectively. The effect of dye concentration on dye decolorization and 100% decolorization activity was achieved in dye concentration between 50-300 ppm. Lac-PHEMAPA cryogel discs maintained 80% of its decolorization activity after six cycles. Consequently, the PHEMAPA cryogel discs are promising materials for immobilizing laccase. The Lac-PHEMAPA has a rapid dye decolorization in a broad range of temperature. The preparation is furthermore very stable and activity is preserved during storage.</p>}},
  author       = {{Perçin, Işik and ARACAGÖK, Yusuf Doruk and Idil, Neslihan and Denizli, Adil and Mattiasson, Bo}},
  issn         = {{1300-0527}},
  keywords     = {{Cryogel; Laccase; N-methacryloyl-(L)-phenylalanine methyl ester; Reactive blue; Textile dye decolorization}},
  language     = {{eng}},
  number       = {{5}},
  pages        = {{1353--1365}},
  publisher    = {{Scientific Technical Research Council Turkey-Tubitak}},
  series       = {{Turkish Journal of Chemistry}},
  title        = {{Laccase bound to cryogel functionalized with phenylalanine for the decolorization of textile dyes}},
  url          = {{http://dx.doi.org/10.3906/kim-2106-16}},
  doi          = {{10.3906/kim-2106-16}},
  volume       = {{45}},
  year         = {{2021}},
}