Laccase bound to cryogel functionalized with phenylalanine for the decolorization of textile dyes
(2021) In Turkish Journal of Chemistry 45(5). p.1353-1365- Abstract
In this study, amino acid functionalized poly(2-hydroxyethyl methacrylate-N-methacrylolyl-l-phenylalanine) [PHEMAPA] cryogel discs were prepared. In this respect, phenylalanine containing N-methacryloyl-(L)-phenylalanine methyl ester (MAPA) was polymerized with 2-hydroxyethyl methacrylate (HEMA) without requirement of any activation step. Laccase bound poly(2-hydroxyethyl methacrylate-N-methacryloyl-l-phenylalanine) [Lac-PHEMAPA] cryogel discs were applied for decolorization of Reactive Blue-247 (RB-247). The ability of Lac-PHEMAPA cryogel discs on dye decolorization was found to be as 90% in 2 h and even more within 4h. The decolorization activities of 86% and 73% were observed at relatively low (4°C) and high (60°C) temperatures,... (More)
In this study, amino acid functionalized poly(2-hydroxyethyl methacrylate-N-methacrylolyl-l-phenylalanine) [PHEMAPA] cryogel discs were prepared. In this respect, phenylalanine containing N-methacryloyl-(L)-phenylalanine methyl ester (MAPA) was polymerized with 2-hydroxyethyl methacrylate (HEMA) without requirement of any activation step. Laccase bound poly(2-hydroxyethyl methacrylate-N-methacryloyl-l-phenylalanine) [Lac-PHEMAPA] cryogel discs were applied for decolorization of Reactive Blue-247 (RB-247). The ability of Lac-PHEMAPA cryogel discs on dye decolorization was found to be as 90% in 2 h and even more within 4h. The decolorization activities of 86% and 73% were observed at relatively low (4°C) and high (60°C) temperatures, respectively. The effect of dye concentration on dye decolorization and 100% decolorization activity was achieved in dye concentration between 50-300 ppm. Lac-PHEMAPA cryogel discs maintained 80% of its decolorization activity after six cycles. Consequently, the PHEMAPA cryogel discs are promising materials for immobilizing laccase. The Lac-PHEMAPA has a rapid dye decolorization in a broad range of temperature. The preparation is furthermore very stable and activity is preserved during storage.
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- author
- Perçin, Işik ; ARACAGÖK, Yusuf Doruk ; Idil, Neslihan ; Denizli, Adil and Mattiasson, Bo LU
- organization
- publishing date
- 2021
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Cryogel, Laccase, N-methacryloyl-(L)-phenylalanine methyl ester, Reactive blue, Textile dye decolorization
- in
- Turkish Journal of Chemistry
- volume
- 45
- issue
- 5
- pages
- 13 pages
- publisher
- Scientific Technical Research Council Turkey-Tubitak
- external identifiers
-
- pmid:34849053
- scopus:85117584537
- ISSN
- 1300-0527
- DOI
- 10.3906/kim-2106-16
- language
- English
- LU publication?
- yes
- additional info
- Publisher Copyright: © 2021 TUBITAK. All rights reserved.
- id
- 2bce2898-5107-497d-a011-b6a4f5f3fd4d
- date added to LUP
- 2021-11-05 11:32:07
- date last changed
- 2025-01-13 17:07:13
@article{2bce2898-5107-497d-a011-b6a4f5f3fd4d,
abstract = {{<p>In this study, amino acid functionalized poly(2-hydroxyethyl methacrylate-N-methacrylolyl-l-phenylalanine) [PHEMAPA] cryogel discs were prepared. In this respect, phenylalanine containing N-methacryloyl-(L)-phenylalanine methyl ester (MAPA) was polymerized with 2-hydroxyethyl methacrylate (HEMA) without requirement of any activation step. Laccase bound poly(2-hydroxyethyl methacrylate-N-methacryloyl-l-phenylalanine) [Lac-PHEMAPA] cryogel discs were applied for decolorization of Reactive Blue-247 (RB-247). The ability of Lac-PHEMAPA cryogel discs on dye decolorization was found to be as 90% in 2 h and even more within 4h. The decolorization activities of 86% and 73% were observed at relatively low (4°C) and high (60°C) temperatures, respectively. The effect of dye concentration on dye decolorization and 100% decolorization activity was achieved in dye concentration between 50-300 ppm. Lac-PHEMAPA cryogel discs maintained 80% of its decolorization activity after six cycles. Consequently, the PHEMAPA cryogel discs are promising materials for immobilizing laccase. The Lac-PHEMAPA has a rapid dye decolorization in a broad range of temperature. The preparation is furthermore very stable and activity is preserved during storage.</p>}},
author = {{Perçin, Işik and ARACAGÖK, Yusuf Doruk and Idil, Neslihan and Denizli, Adil and Mattiasson, Bo}},
issn = {{1300-0527}},
keywords = {{Cryogel; Laccase; N-methacryloyl-(L)-phenylalanine methyl ester; Reactive blue; Textile dye decolorization}},
language = {{eng}},
number = {{5}},
pages = {{1353--1365}},
publisher = {{Scientific Technical Research Council Turkey-Tubitak}},
series = {{Turkish Journal of Chemistry}},
title = {{Laccase bound to cryogel functionalized with phenylalanine for the decolorization of textile dyes}},
url = {{http://dx.doi.org/10.3906/kim-2106-16}},
doi = {{10.3906/kim-2106-16}},
volume = {{45}},
year = {{2021}},
}