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A Diels-Alder Approach to a Communesin Model: A/B-Cyclization Route

Sanzone, Angelo LU and Somfai, Peter LU (2015) In European Journal of Organic Chemistry p.3441-3449
Abstract
Compound 3, a model system for communesin F, was approached by using a Diels-Alder reaction for the introduction of the vicinal quaternary stereocentres. Subsequent introduction of A/B-ring system followed by D/E-ring closure gave hexacyclic system 22. All attempts to reduce this material to give compound 3 were, however, unproductive.
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author
and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Polycycles, Alkaloids, Natural products, Cyclization, Synthesis design
in
European Journal of Organic Chemistry
issue
16
pages
3441 - 3449
publisher
John Wiley and Sons
external identifiers
  • wos:000355265000006
  • scopus:84934873244
ISSN
1434-193X
DOI
10.1002/ejoc.201500177
language
English
LU publication?
yes
id
2e589828-4e53-4a8d-bd37-c7fb3501e853 (old id 7410597)
date added to LUP
2016-04-01 10:37:09
date last changed
2021-01-06 04:21:27
@article{2e589828-4e53-4a8d-bd37-c7fb3501e853,
  abstract     = {Compound 3, a model system for communesin F, was approached by using a Diels-Alder reaction for the introduction of the vicinal quaternary stereocentres. Subsequent introduction of A/B-ring system followed by D/E-ring closure gave hexacyclic system 22. All attempts to reduce this material to give compound 3 were, however, unproductive.},
  author       = {Sanzone, Angelo and Somfai, Peter},
  issn         = {1434-193X},
  language     = {eng},
  number       = {16},
  pages        = {3441--3449},
  publisher    = {John Wiley and Sons},
  series       = {European Journal of Organic Chemistry},
  title        = {A Diels-Alder Approach to a Communesin Model: A/B-Cyclization Route},
  url          = {http://dx.doi.org/10.1002/ejoc.201500177},
  doi          = {10.1002/ejoc.201500177},
  year         = {2015},
}