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trans-Di-mu-chloro-bis[(dimethyl sulfoxide-kappa S)phenylplatinum(II)]

Nilsson, Patrik LU and Wendt, Ola LU (2002) In Acta Crystallographica Section E: Structure Reports Online 58(part 11). p.639-640
Abstract
The title compound, [Pt2Cl2(C6H5)2(C2H6OS)2] or [Pt([bold mu]-Cl)Ph(dmso)]2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is centrosymmetric, thus necessitating a trans configuration, with one dmso and one phenyl ligand coordinated to each Pt atom. The two Pt-Cl, the Pt-S and the Pt-C distances are 2.366 (2), 2.475 (2), 2.192 (2) and 1.997 (7) Å, respectively.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
58
issue
part 11
pages
639 - 640
publisher
Wiley-Blackwell
external identifiers
  • wos:000180719300011
ISSN
1600-5368
DOI
10.1107/S1600536802018421
language
English
LU publication?
yes
id
f5721c2d-7a81-45c2-a31d-0c651c1bac03 (old id 318833)
date added to LUP
2007-11-19 16:08:23
date last changed
2016-04-16 05:34:52
@article{f5721c2d-7a81-45c2-a31d-0c651c1bac03,
  abstract     = {The title compound, [Pt2Cl2(C6H5)2(C2H6OS)2] or [Pt([bold mu]-Cl)Ph(dmso)]2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is centrosymmetric, thus necessitating a trans configuration, with one dmso and one phenyl ligand coordinated to each Pt atom. The two Pt-Cl, the Pt-S and the Pt-C distances are 2.366 (2), 2.475 (2), 2.192 (2) and 1.997 (7) Å, respectively.},
  author       = {Nilsson, Patrik and Wendt, Ola},
  issn         = {1600-5368},
  language     = {eng},
  number       = {part 11},
  pages        = {639--640},
  publisher    = {Wiley-Blackwell},
  series       = {Acta Crystallographica Section E: Structure Reports Online},
  title        = {trans-Di-mu-chloro-bis[(dimethyl sulfoxide-kappa S)phenylplatinum(II)]},
  url          = {http://dx.doi.org/10.1107/S1600536802018421},
  volume       = {58},
  year         = {2002},
}