trans-Di-mu-chloro-bis[(dimethyl sulfoxide-kappa S)phenylplatinum(II)]
(2002) In Acta Crystallographica Section E: Structure Reports Online 58(part 11). p.639-640- Abstract
- The title compound, [Pt2Cl2(C6H5)2(C2H6OS)2] or [Pt([bold mu]-Cl)Ph(dmso)]2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is centrosymmetric, thus necessitating a trans configuration, with one dmso and one phenyl ligand coordinated to each Pt atom. The two Pt-Cl, the Pt-S and the Pt-C distances are 2.366 (2), 2.475 (2), 2.192 (2) and 1.997 (7) Å, respectively.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/318833
- author
- Nilsson, Patrik LU and Wendt, Ola LU
- organization
- publishing date
- 2002
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Acta Crystallographica Section E: Structure Reports Online
- volume
- 58
- issue
- part 11
- pages
- 639 - 640
- publisher
- International Union of Crystallography
- external identifiers
-
- wos:000180719300011
- ISSN
- 1600-5368
- DOI
- 10.1107/S1600536802018421
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Inorganic chemistry (ceased) (LUR000010)
- id
- f5721c2d-7a81-45c2-a31d-0c651c1bac03 (old id 318833)
- date added to LUP
- 2016-04-01 17:14:15
- date last changed
- 2018-11-21 20:47:42
@article{f5721c2d-7a81-45c2-a31d-0c651c1bac03, abstract = {{The title compound, [Pt2Cl2(C6H5)2(C2H6OS)2] or [Pt([bold mu]-Cl)Ph(dmso)]2 (dmso is dimethyl sulfoxide), is a dimer with a pseudo square-planar coordination geometry around the Pt atoms, with two bridging Cl ligands creating a four-membered ring at the centre of the dimer. The complex is centrosymmetric, thus necessitating a trans configuration, with one dmso and one phenyl ligand coordinated to each Pt atom. The two Pt-Cl, the Pt-S and the Pt-C distances are 2.366 (2), 2.475 (2), 2.192 (2) and 1.997 (7) Å, respectively.}}, author = {{Nilsson, Patrik and Wendt, Ola}}, issn = {{1600-5368}}, language = {{eng}}, number = {{part 11}}, pages = {{639--640}}, publisher = {{International Union of Crystallography}}, series = {{Acta Crystallographica Section E: Structure Reports Online}}, title = {{trans-Di-mu-chloro-bis[(dimethyl sulfoxide-kappa S)phenylplatinum(II)]}}, url = {{http://dx.doi.org/10.1107/S1600536802018421}}, doi = {{10.1107/S1600536802018421}}, volume = {{58}}, year = {{2002}}, }