The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine
(2012) In Inorganica Chimica Acta 392. p.490-493- Abstract
- Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3190087
- author
- Nilsson, Jessica LU ; Colbran, Stephen B. ; Behrens, Ulrich ; Rehder, Dieter and Nordlander, Ebbe LU
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Vanadium, Vanadyl cation, Reduction, Ascidians
- in
- Inorganica Chimica Acta
- volume
- 392
- pages
- 490 - 493
- publisher
- Elsevier
- external identifiers
-
- wos:000308696200071
- scopus:84865745221
- ISSN
- 0020-1693
- DOI
- 10.1016/j.ica.2012.04.041
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- 6d3acc03-af8d-4ea6-b0c6-c3cabf3151b2 (old id 3190087)
- date added to LUP
- 2016-04-01 13:52:01
- date last changed
- 2022-01-27 21:32:45
@article{6d3acc03-af8d-4ea6-b0c6-c3cabf3151b2, abstract = {{Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.}}, author = {{Nilsson, Jessica and Colbran, Stephen B. and Behrens, Ulrich and Rehder, Dieter and Nordlander, Ebbe}}, issn = {{0020-1693}}, keywords = {{Vanadium; Vanadyl cation; Reduction; Ascidians}}, language = {{eng}}, pages = {{490--493}}, publisher = {{Elsevier}}, series = {{Inorganica Chimica Acta}}, title = {{The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine}}, url = {{http://dx.doi.org/10.1016/j.ica.2012.04.041}}, doi = {{10.1016/j.ica.2012.04.041}}, volume = {{392}}, year = {{2012}}, }