Advanced

The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine

Nilsson, Jessica LU ; Colbran, Stephen B.; Behrens, Ulrich; Rehder, Dieter and Nordlander, Ebbe LU (2012) In Inorganica Chimica Acta 392. p.490-493
Abstract
Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Vanadium, Vanadyl cation, Reduction, Ascidians
in
Inorganica Chimica Acta
volume
392
pages
490 - 493
publisher
Elsevier
external identifiers
  • wos:000308696200071
  • scopus:84865745221
ISSN
0020-1693
DOI
10.1016/j.ica.2012.04.041
language
English
LU publication?
yes
id
6d3acc03-af8d-4ea6-b0c6-c3cabf3151b2 (old id 3190087)
date added to LUP
2012-12-04 08:18:03
date last changed
2017-01-01 05:55:24
@article{6d3acc03-af8d-4ea6-b0c6-c3cabf3151b2,
  abstract     = {Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.},
  author       = {Nilsson, Jessica and Colbran, Stephen B. and Behrens, Ulrich and Rehder, Dieter and Nordlander, Ebbe},
  issn         = {0020-1693},
  keyword      = {Vanadium,Vanadyl cation,Reduction,Ascidians},
  language     = {eng},
  pages        = {490--493},
  publisher    = {Elsevier},
  series       = {Inorganica Chimica Acta},
  title        = {The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine},
  url          = {http://dx.doi.org/10.1016/j.ica.2012.04.041},
  volume       = {392},
  year         = {2012},
}