Rearrangement of spiro [2H-1-benzopyran-2,2 '-[2H] indoles] to pyrrolo[1,2-a]indole derivatives
(2002) In Journal of Heterocyclic Chemistry 39(6). p.1123-1128- Abstract
- Heating of 1'-(N-substituted carbamoyl)methylspiro[2H-1-benzopyran-2,2'-[2H]indoles] with potassium hydroxide in ethanol yields diastereomeric 5a,13-methano-6H-1,3-benzoxazepino[3,2-a]indole-12-carboxamides. Reduction of the latter with sodium borohydride affords 1,2,3,9a-tetrahydro-2-hydroxyaryl-9H-pyrrolo[1,2-a]indole-3-carboxamides .
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/319797
- author
- Martynaitis, V ; Sackus, A and Berg, Ulf LU
- organization
- publishing date
- 2002
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Heterocyclic Chemistry
- volume
- 39
- issue
- 6
- pages
- 1123 - 1128
- publisher
- Journal of Heterocyclic Chemistry
- external identifiers
-
- wos:000180476400002
- scopus:0036875684
- ISSN
- 0022-152X
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- 8ad6b23b-fe7f-4a71-a9f1-038265e16c63 (old id 319797)
- date added to LUP
- 2016-04-01 15:38:47
- date last changed
- 2022-02-27 08:03:06
@article{8ad6b23b-fe7f-4a71-a9f1-038265e16c63, abstract = {{Heating of 1'-(N-substituted carbamoyl)methylspiro[2H-1-benzopyran-2,2'-[2H]indoles] with potassium hydroxide in ethanol yields diastereomeric 5a,13-methano-6H-1,3-benzoxazepino[3,2-a]indole-12-carboxamides. Reduction of the latter with sodium borohydride affords 1,2,3,9a-tetrahydro-2-hydroxyaryl-9H-pyrrolo[1,2-a]indole-3-carboxamides .}}, author = {{Martynaitis, V and Sackus, A and Berg, Ulf}}, issn = {{0022-152X}}, language = {{eng}}, number = {{6}}, pages = {{1123--1128}}, publisher = {{Journal of Heterocyclic Chemistry}}, series = {{Journal of Heterocyclic Chemistry}}, title = {{Rearrangement of spiro [2H-1-benzopyran-2,2 '-[2H] indoles] to pyrrolo[1,2-a]indole derivatives}}, volume = {{39}}, year = {{2002}}, }