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Synthesis and Spectroscopic Characterisation of a Heterodinuclear Iron(III)-Copper(II) Complex Based on an Asymmetric Dinucleating Ligand System

Heims, Florian; Mereacre, Valeriu; Ciancetta, Antonella LU ; Mebs, Stefan; Powell, Annie K.; Greco, Claudio and Ray, Kallol (2012) In European Journal of Inorganic Chemistry p.4565-4569
Abstract
The site-directed generation of a heterodinuclear FeIIICuII complex by using a new asymmetric dinucleating ligand FloH is reported. The iron(III) ion is introduced first on the preferential metal-binding site of the ligand that leads to the formation of the thermodynamically favored five-membered chelate rings upon metal-binding. Copper(II) is introduced in the next step. The stepwise metalation strategy reported here may be extended to the preparation of other heterometallic complexes with the view of avoiding a statistical distribution. Such complexes can offer novel spectroscopic properties, electronic structures, and reactivities in comparison to their homometallic analogues.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Bioinorganic chemistry, Unsymmetric ligands, Heterometallic complexes, Copper, Iron
in
European Journal of Inorganic Chemistry
issue
29
pages
4565 - 4569
publisher
John Wiley & Sons
external identifiers
  • wos:000309467600005
  • scopus:84867060270
ISSN
1099-0682
DOI
10.1002/ejic.201200156
language
English
LU publication?
yes
id
f9f6789c-083a-49f1-bae7-4a7a92d8b0fd (old id 3244543)
date added to LUP
2012-12-27 11:12:50
date last changed
2017-10-08 03:19:49
@article{f9f6789c-083a-49f1-bae7-4a7a92d8b0fd,
  abstract     = {The site-directed generation of a heterodinuclear FeIIICuII complex by using a new asymmetric dinucleating ligand FloH is reported. The iron(III) ion is introduced first on the preferential metal-binding site of the ligand that leads to the formation of the thermodynamically favored five-membered chelate rings upon metal-binding. Copper(II) is introduced in the next step. The stepwise metalation strategy reported here may be extended to the preparation of other heterometallic complexes with the view of avoiding a statistical distribution. Such complexes can offer novel spectroscopic properties, electronic structures, and reactivities in comparison to their homometallic analogues.},
  author       = {Heims, Florian and Mereacre, Valeriu and Ciancetta, Antonella and Mebs, Stefan and Powell, Annie K. and Greco, Claudio and Ray, Kallol},
  issn         = {1099-0682},
  keyword      = {Bioinorganic chemistry,Unsymmetric ligands,Heterometallic complexes,Copper,Iron},
  language     = {eng},
  number       = {29},
  pages        = {4565--4569},
  publisher    = {John Wiley & Sons},
  series       = {European Journal of Inorganic Chemistry},
  title        = {Synthesis and Spectroscopic Characterisation of a Heterodinuclear Iron(III)-Copper(II) Complex Based on an Asymmetric Dinucleating Ligand System},
  url          = {http://dx.doi.org/10.1002/ejic.201200156},
  year         = {2012},
}