Anisotropic ultrafast dissociation probed by the Doppler effect in resonant photoemission from CF4
(2003) In Physical Review Letters 90(23: 233006).- Abstract
- The resonant Auger spectrum from the decay of F 1s-excited CF4 is measured. Several lines exhibit a nondispersive kinetic energy as the exciting photon energy is tuned through the resonance region. The F 1s(-1) atomiclike Auger line is split into two components due to the emission of Auger electrons by a fragment in motion, when electron emission is observed along the polarization vector of the light. This Doppler splitting is direct evidence that the core excitation leads to T-d-->C-3v symmetry lowering, by elongation of a specific C-F bond preferentially aligned along the polarization vector of the incident photon.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/308368
- author
- organization
- publishing date
- 2003
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Physical Review Letters
- volume
- 90
- issue
- 23: 233006
- article number
- 233006
- publisher
- American Physical Society
- external identifiers
-
- wos:000183483500019
- scopus:0042844706
- ISSN
- 1079-7114
- DOI
- 10.1103/PhysRevLett.90.233006
- language
- English
- LU publication?
- yes
- id
- 328a7174-c59e-498f-8605-d2c78156c858 (old id 308368)
- date added to LUP
- 2016-04-01 11:46:20
- date last changed
- 2024-01-22 17:44:45
@article{328a7174-c59e-498f-8605-d2c78156c858, abstract = {{The resonant Auger spectrum from the decay of F 1s-excited CF4 is measured. Several lines exhibit a nondispersive kinetic energy as the exciting photon energy is tuned through the resonance region. The F 1s(-1) atomiclike Auger line is split into two components due to the emission of Auger electrons by a fragment in motion, when electron emission is observed along the polarization vector of the light. This Doppler splitting is direct evidence that the core excitation leads to T-d-->C-3v symmetry lowering, by elongation of a specific C-F bond preferentially aligned along the polarization vector of the incident photon.}}, author = {{Ueda, K and Kitajima, M and De Fanis, A and Furuta, T and Shindo, H and Tanaka, H and Okada, K and Feifel, R and Ristinmaa Sörensen, Stacey and Yoshida, H and Senba, Y}}, issn = {{1079-7114}}, language = {{eng}}, number = {{23: 233006}}, publisher = {{American Physical Society}}, series = {{Physical Review Letters}}, title = {{Anisotropic ultrafast dissociation probed by the Doppler effect in resonant photoemission from CF4}}, url = {{http://dx.doi.org/10.1103/PhysRevLett.90.233006}}, doi = {{10.1103/PhysRevLett.90.233006}}, volume = {{90}}, year = {{2003}}, }