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The vibrational spectra of methyl groups in methylthiolate and methoxy adsorbed on Cu(100)

Andersson, Martin LU and Uvdal, Per LU (2002) In Langmuir 18(10). p.3759-3762
Abstract
We show that the difference in the infrared vibrational spectrum of C-H stretch modes arising from the methyl group of two surface intermediates, methylthiolate and methoxy, originates from the difference in the methyl deformation modes frequencies of the two intermediates. Importantly, while the vibrational fingerprint of the two methyl groups are not transferable between the intermediates, the Fermi resonance coupling constants of the methyl group are.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Langmuir
volume
18
issue
10
pages
3759 - 3762
publisher
The American Chemical Society
external identifiers
  • wos:000175500300001
  • scopus:0037076625
ISSN
0743-7463
DOI
10.1021/la011249c
language
English
LU publication?
yes
id
a4de4371-f0cc-425a-98b0-4b776ce42dbb (old id 337853)
date added to LUP
2007-08-07 09:44:09
date last changed
2017-01-01 05:10:57
@article{a4de4371-f0cc-425a-98b0-4b776ce42dbb,
  abstract     = {We show that the difference in the infrared vibrational spectrum of C-H stretch modes arising from the methyl group of two surface intermediates, methylthiolate and methoxy, originates from the difference in the methyl deformation modes frequencies of the two intermediates. Importantly, while the vibrational fingerprint of the two methyl groups are not transferable between the intermediates, the Fermi resonance coupling constants of the methyl group are.},
  author       = {Andersson, Martin and Uvdal, Per},
  issn         = {0743-7463},
  language     = {eng},
  number       = {10},
  pages        = {3759--3762},
  publisher    = {The American Chemical Society},
  series       = {Langmuir},
  title        = {The vibrational spectra of methyl groups in methylthiolate and methoxy adsorbed on Cu(100)},
  url          = {http://dx.doi.org/10.1021/la011249c},
  volume       = {18},
  year         = {2002},
}