Li-7 NMR measurements of polymer gel electrolytes
(2002) In Solid State Ionics 147(3-4). p.303-307- Abstract
- Ion conducting polymer gels prepared from (ethylene oxide)(n) grafted methacrylates, ethylene carbonate (EC), gamma butyrolactone (gBL), and lithium hexafluorophosphate are studied by means of nuclear magnetic resonance spectroscopy, This study shows that there are at least two possible lithium sites with different mobility. The lithium-ions with lower mobility dominate at room temperature, but this is changed as the temperature is increased. The NMR results also show that the Li-7 spin-spin relaxation time decreases with increasing length of the grafted ethylene oxide side chains, indicating a stronger interaction between the polymer and the Li-ions, and hence, a lower mobility of the Li-ions. (C) 2002 Elsevier Science B.V. All rights... (More)
- Ion conducting polymer gels prepared from (ethylene oxide)(n) grafted methacrylates, ethylene carbonate (EC), gamma butyrolactone (gBL), and lithium hexafluorophosphate are studied by means of nuclear magnetic resonance spectroscopy, This study shows that there are at least two possible lithium sites with different mobility. The lithium-ions with lower mobility dominate at room temperature, but this is changed as the temperature is increased. The NMR results also show that the Li-7 spin-spin relaxation time decreases with increasing length of the grafted ethylene oxide side chains, indicating a stronger interaction between the polymer and the Li-ions, and hence, a lower mobility of the Li-ions. (C) 2002 Elsevier Science B.V. All rights reserved. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/338763
- author
- Adebahr, Josefina ; Forsyth, M ; MacFarlane, DR ; Gavelin, Patrik LU and Jacobsson, P
- organization
- publishing date
- 2002
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- polymer gel electrolyte, mobility, NMR spectroscopy, ionic interaction
- in
- Solid State Ionics
- volume
- 147
- issue
- 3-4
- pages
- 303 - 307
- publisher
- Elsevier
- external identifiers
-
- wos:000175219600014
- scopus:0036535485
- ISSN
- 0167-2738
- DOI
- 10.1016/S0167-2738(02)00014-0
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- 72a498d2-9b0a-4afc-8b0c-ca2a2b950850 (old id 338763)
- date added to LUP
- 2016-04-01 11:40:54
- date last changed
- 2022-03-28 01:31:27
@article{72a498d2-9b0a-4afc-8b0c-ca2a2b950850,
abstract = {{Ion conducting polymer gels prepared from (ethylene oxide)(n) grafted methacrylates, ethylene carbonate (EC), gamma butyrolactone (gBL), and lithium hexafluorophosphate are studied by means of nuclear magnetic resonance spectroscopy, This study shows that there are at least two possible lithium sites with different mobility. The lithium-ions with lower mobility dominate at room temperature, but this is changed as the temperature is increased. The NMR results also show that the Li-7 spin-spin relaxation time decreases with increasing length of the grafted ethylene oxide side chains, indicating a stronger interaction between the polymer and the Li-ions, and hence, a lower mobility of the Li-ions. (C) 2002 Elsevier Science B.V. All rights reserved.}},
author = {{Adebahr, Josefina and Forsyth, M and MacFarlane, DR and Gavelin, Patrik and Jacobsson, P}},
issn = {{0167-2738}},
keywords = {{polymer gel electrolyte; mobility; NMR spectroscopy; ionic interaction}},
language = {{eng}},
number = {{3-4}},
pages = {{303--307}},
publisher = {{Elsevier}},
series = {{Solid State Ionics}},
title = {{Li-7 NMR measurements of polymer gel electrolytes}},
url = {{http://dx.doi.org/10.1016/S0167-2738(02)00014-0}},
doi = {{10.1016/S0167-2738(02)00014-0}},
volume = {{147}},
year = {{2002}},
}