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Unusual C-H bond activation-aldol condensation of aromatic aldehydes with the methyl group of a carbene-like triosmium cluster

Tunik, SP; Balova, IA; Borovitov, ME; Nordlander, Ebbe LU ; Haukka, M and Pakkanen, TA (2002) In Journal of the Chemical Society. Dalton Transactions p.827-828
Abstract
Reactions of the triosmium cluster [HOs3(CO)(10)(eta(1):eta(1)-OC4H2CCH3)] with a series of aromatic aldehydes under mild conditions result in condensation of the ligand methyl group with the aldehyde C=O moiety to give typical aldol condensation products.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of the Chemical Society. Dalton Transactions
issue
6
pages
827 - 828
publisher
Royal Society of Chemistry
external identifiers
  • wos:000174433000004
  • scopus:0036006311
ISSN
1472-7773
DOI
10.1039/b200707j
language
English
LU publication?
yes
id
98107a9e-a164-41c0-9a6e-6c5f10b670af (old id 342002)
date added to LUP
2007-11-16 16:56:37
date last changed
2017-08-13 04:23:09
@article{98107a9e-a164-41c0-9a6e-6c5f10b670af,
  abstract     = {Reactions of the triosmium cluster [HOs3(CO)(10)(eta(1):eta(1)-OC4H2CCH3)] with a series of aromatic aldehydes under mild conditions result in condensation of the ligand methyl group with the aldehyde C=O moiety to give typical aldol condensation products.},
  author       = {Tunik, SP and Balova, IA and Borovitov, ME and Nordlander, Ebbe and Haukka, M and Pakkanen, TA},
  issn         = {1472-7773},
  language     = {eng},
  number       = {6},
  pages        = {827--828},
  publisher    = {Royal Society of Chemistry},
  series       = {Journal of the Chemical Society. Dalton Transactions},
  title        = {Unusual C-H bond activation-aldol condensation of aromatic aldehydes with the methyl group of a carbene-like triosmium cluster},
  url          = {http://dx.doi.org/10.1039/b200707j},
  year         = {2002},
}