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cis-{2,6-Bis[(di-tert-butyl-phosphan-yl)meth-yl]cyclo-hexyl-κ(3) P,C (1),P'}chloridopalladium(II).

Olsson, Daniel LU ; van Rensburg, Jacobus LU and Wendt, Ola LU (2012) In Acta Crystallographica Section E: Structure Reports Online 68(Pt 12). p.1513-1513
Abstract
The Pd atom in the title compound, [Pd(CHP)Cl], has a distorted square-planar CClP coordination geometry with the ,,'-tridentate ligand forming two five-membered metallacycles. The cyclo-hexane ring is aligned with the Pd coordination plane due to C-H activation in an equatorial position, giving a tri-equatorial conformation of the cyclo-hexyl ring.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
68
issue
Pt 12
pages
1513 - 1513
publisher
Wiley-Blackwell
external identifiers
  • pmid:23468725
  • scopus:84870946465
ISSN
1600-5368
DOI
10.1107/S1600536812047022
language
English
LU publication?
yes
id
8b4d7473-53ee-4fd1-bb1c-845d9129f41c (old id 3628475)
date added to LUP
2013-04-10 17:34:43
date last changed
2017-01-01 05:30:17
@article{8b4d7473-53ee-4fd1-bb1c-845d9129f41c,
  abstract     = {The Pd atom in the title compound, [Pd(CHP)Cl], has a distorted square-planar CClP coordination geometry with the ,,'-tridentate ligand forming two five-membered metallacycles. The cyclo-hexane ring is aligned with the Pd coordination plane due to C-H activation in an equatorial position, giving a tri-equatorial conformation of the cyclo-hexyl ring.},
  author       = {Olsson, Daniel and van Rensburg, Jacobus and Wendt, Ola},
  issn         = {1600-5368},
  language     = {eng},
  number       = {Pt 12},
  pages        = {1513--1513},
  publisher    = {Wiley-Blackwell},
  series       = {Acta Crystallographica Section E: Structure Reports Online},
  title        = {cis-{2,6-Bis[(di-tert-butyl-phosphan-yl)meth-yl]cyclo-hexyl-κ(3) P,C (1),P'}chloridopalladium(II).},
  url          = {http://dx.doi.org/10.1107/S1600536812047022},
  volume       = {68},
  year         = {2012},
}