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A Microcalorimetric Study of Macrocyclic Complexes in Aqueous Solution

Stödeman, Magnus LU (1998)
Abstract
The present work involves a microcalorimetric characterization of the interactions among macrocyclic compounds and aliphatic molecules in aqueous solution. The macrocyclic compounds used in the study are a-,b- and g-cyclodextrin and 25,26,27,28-tetrahydroxycalix[4]arene-5,11,17,23- tetrasulphonate. The results include enthalpies, entropies, standard Gibb's energies and heat capacities of the interactions.



Further, an experimental model for a vaporization calorimeter has been constructed, tested and discussed.
Please use this url to cite or link to this publication:
author
supervisor
opponent
  • Prof Zielenkiewicz, W.
organization
publishing date
type
Thesis
publication status
published
subject
keywords
Chemistry, Aqueous Solution, Calixarene, Cyclodextrin, Vaporization, Macrocyclic compounds, Microcalorimetry, Kemi
pages
236 pages
publisher
Thermochemistry Division, Chemical Center, Lund University
defense location
Lecture Hall F, Chemical Center, Lund
defense date
1998-03-13 10:15:00
language
English
LU publication?
yes
additional info
Article: Scope of microcalorimetry in the area of macrocyclic chemistryStödeman, M. and Wadsö, I.Pure & Appl. Chem. 1995, 67(7), 1059-1068 Article: Microcalorimetric Titration of a-Cyclodextrin with Some Straight-chain a,w-Dicarboxylates in Aqueous Solution at Different TemperaturesGómez-Orellana, I., Hallén, D. and Stödeman, M.J. Chem. Soc. Faraday Trans. 1994, 90(22),3397-3400 Article: A Thermodynamic Study on Interactions Among a-Cyclodextrin and Straight-chain Alkyl Derivatives in Aqueous SolutionStödeman, M, Gómez-Orellana, I. and Hallén, D.J. Chem. Soc. Faraday Trans.; Submitted Article: Interactions of a-, b- and g-Cyclodextrin with bicyclo[2.2.2]octane-1,4-derivatives in aqueous solution and in gas phase - a microcalorimetric study and molecular modellingStödeman, M., Berg, U. and Svensson, A.J. Chem. Soc. Faraday Trans.; Accepted Article: Microcalorimetric Titration of a tetra-p-Sulphonated Calix[4]Arene with Alkyl Ammonium ions in Aqueous SolutionStödeman, M. and Dhar, N.J. Chem. Soc. Faraday Trans.; Accepted Article: Microcalorimetric titration of a tetra-p-sulphonated calix[4]arene with a,w-alkyl diammonium ions in aqueous solutionStödeman, M. and Dhar, N.Thermochimica Acta; Submitted
id
a1145d3a-ca64-464b-a81b-dd4abc06d10e (old id 38421)
date added to LUP
2016-04-04 11:19:53
date last changed
2018-11-21 21:04:09
@phdthesis{a1145d3a-ca64-464b-a81b-dd4abc06d10e,
  abstract     = {{The present work involves a microcalorimetric characterization of the interactions among macrocyclic compounds and aliphatic molecules in aqueous solution. The macrocyclic compounds used in the study are a-,b- and g-cyclodextrin and 25,26,27,28-tetrahydroxycalix[4]arene-5,11,17,23- tetrasulphonate. The results include enthalpies, entropies, standard Gibb's energies and heat capacities of the interactions.<br/><br>
<br/><br>
Further, an experimental model for a vaporization calorimeter has been constructed, tested and discussed.}},
  author       = {{Stödeman, Magnus}},
  keywords     = {{Chemistry; Aqueous Solution; Calixarene; Cyclodextrin; Vaporization; Macrocyclic compounds; Microcalorimetry; Kemi}},
  language     = {{eng}},
  publisher    = {{Thermochemistry Division, Chemical Center, Lund University}},
  school       = {{Lund University}},
  title        = {{A Microcalorimetric Study of Macrocyclic Complexes in Aqueous Solution}},
  year         = {{1998}},
}