A model for prediction of limestone dissolution in wet flue gas desulfurization applications
(1997) In Industrial & Engineering Chemistry Research 36(9). p.3889-3897- Abstract
- A model has been developed to predict the dissolution rate of a limestone slurry as a function of particle size distribution and limestone conversion. The model is based on basic mass-transfer theory and includes a factor allowing the flux of calcium ions from the limestone surface to vary with the fraction dissolved. Changes in the flux with the fraction dissolved have been reported to be caused by the presence of sulfite but can also be caused by accumulation of inerts at the liquid-solid interface and/or by changes in the effective mass-transfer area. Calculations show that the decrease in flux reported for sulfites can have a significant impact on the slurry conditions within the reaction tank, i.e., impact on the limestone conversion... (More)
- A model has been developed to predict the dissolution rate of a limestone slurry as a function of particle size distribution and limestone conversion. The model is based on basic mass-transfer theory and includes a factor allowing the flux of calcium ions from the limestone surface to vary with the fraction dissolved. Changes in the flux with the fraction dissolved have been reported to be caused by the presence of sulfite but can also be caused by accumulation of inerts at the liquid-solid interface and/or by changes in the effective mass-transfer area. Calculations show that the decrease in flux reported for sulfites can have a significant impact on the slurry conditions within the reaction tank, i.e., impact on the limestone conversion and the relationship between liquid and solid alkalinity. In the absence of sulfites, the flux from limestone particles has been assumed to be constant with respect to the degree of dissolution. The modeling results have been found to be in good agreement with the measured values of a continuous stirred tank reactor. The model was able to accurately predict the impact of both the particle size distribution and reaction tank residence time on limestone conversion and dissolution rate. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3915504
- author
- Brogren, C and Karlsson, Hans LU
- organization
- publishing date
- 1997
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Industrial & Engineering Chemistry Research
- volume
- 36
- issue
- 9
- pages
- 3889 - 3897
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:A1997XU45200060
- scopus:0031230872
- ISSN
- 0888-5885
- DOI
- 10.1021/ie970030j
- language
- English
- LU publication?
- yes
- id
- a884331f-7e3b-4d1b-8038-57a92ea55675 (old id 3915504)
- date added to LUP
- 2016-04-01 16:36:59
- date last changed
- 2023-11-14 14:43:39
@article{a884331f-7e3b-4d1b-8038-57a92ea55675,
abstract = {{A model has been developed to predict the dissolution rate of a limestone slurry as a function of particle size distribution and limestone conversion. The model is based on basic mass-transfer theory and includes a factor allowing the flux of calcium ions from the limestone surface to vary with the fraction dissolved. Changes in the flux with the fraction dissolved have been reported to be caused by the presence of sulfite but can also be caused by accumulation of inerts at the liquid-solid interface and/or by changes in the effective mass-transfer area. Calculations show that the decrease in flux reported for sulfites can have a significant impact on the slurry conditions within the reaction tank, i.e., impact on the limestone conversion and the relationship between liquid and solid alkalinity. In the absence of sulfites, the flux from limestone particles has been assumed to be constant with respect to the degree of dissolution. The modeling results have been found to be in good agreement with the measured values of a continuous stirred tank reactor. The model was able to accurately predict the impact of both the particle size distribution and reaction tank residence time on limestone conversion and dissolution rate.}},
author = {{Brogren, C and Karlsson, Hans}},
issn = {{0888-5885}},
language = {{eng}},
number = {{9}},
pages = {{3889--3897}},
publisher = {{The American Chemical Society (ACS)}},
series = {{Industrial & Engineering Chemistry Research}},
title = {{A model for prediction of limestone dissolution in wet flue gas desulfurization applications}},
url = {{http://dx.doi.org/10.1021/ie970030j}},
doi = {{10.1021/ie970030j}},
volume = {{36}},
year = {{1997}},
}