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Catalysis as a resonance effect, V. Factors that determine the isokinetic temperature in catalytic reactions

Larsson, Ragnar LU (1999) In Reaction Kinetics and Catalysis Letters 68(1). p.115-124
Abstract
When describing isokinetic effects by the model of selective energy transfer by resonance, it is sometimes found that the frequency of the forcing oscillator is quite different to that of the reacting molecule, i.e."resonance" is not a very good concept to use. By noting that the two frequencies thus found are related to each other as the ratios of small integers, e.g. 4:3, this dilemma is resolved. The investigation covers formic acid decomposition, homogeneous ligand displacement reactions of Ni(DMSO)(6)(2+) and the dissociation of CO2 on metal surfaces.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
resonance effect, isokinetic temperature, catalytic reactions
in
Reaction Kinetics and Catalysis Letters
volume
68
issue
1
pages
115 - 124
publisher
Springer
external identifiers
  • wos:000082492200013
  • scopus:0000519399
ISSN
1588-2837
DOI
10.1007/BF02475493
language
English
LU publication?
yes
id
acd6ef1e-41e0-4153-8634-bfb735796c18 (old id 3917623)
date added to LUP
2013-07-04 09:54:31
date last changed
2017-01-01 04:52:00
@article{acd6ef1e-41e0-4153-8634-bfb735796c18,
  abstract     = {When describing isokinetic effects by the model of selective energy transfer by resonance, it is sometimes found that the frequency of the forcing oscillator is quite different to that of the reacting molecule, i.e."resonance" is not a very good concept to use. By noting that the two frequencies thus found are related to each other as the ratios of small integers, e.g. 4:3, this dilemma is resolved. The investigation covers formic acid decomposition, homogeneous ligand displacement reactions of Ni(DMSO)(6)(2+) and the dissociation of CO2 on metal surfaces.},
  author       = {Larsson, Ragnar},
  issn         = {1588-2837},
  keyword      = {resonance effect,isokinetic temperature,catalytic reactions},
  language     = {eng},
  number       = {1},
  pages        = {115--124},
  publisher    = {Springer},
  series       = {Reaction Kinetics and Catalysis Letters},
  title        = {Catalysis as a resonance effect, V. Factors that determine the isokinetic temperature in catalytic reactions},
  url          = {http://dx.doi.org/10.1007/BF02475493},
  volume       = {68},
  year         = {1999},
}