Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands
(2005) In Inorganica Chimica Acta 358(6). p.1970-1974- Abstract
- Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17){MoO}(8)center dot 10thf center dot hexane, where {MoO}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [{(MoO)-O-IV(S'(2))} {(MoO)-O-V(S'(2))}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/247090
- author
- Behrens, A ; Behrens, U ; Nordlander, Ebbe LU ; Bader, C and Rehder, D
- organization
- publishing date
- 2005
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- molybdopterin, molybdenum complexes, thiofunctional ligands, oxotransferases
- in
- Inorganica Chimica Acta
- volume
- 358
- issue
- 6
- pages
- 1970 - 1974
- publisher
- Elsevier
- external identifiers
-
- wos:000227975700028
- scopus:14844298767
- ISSN
- 0020-1693
- DOI
- 10.1016/j.ica.2004.12.039
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- 3cf87e5d-c9b2-4358-b7b5-11eab2ac472b (old id 247090)
- date added to LUP
- 2016-04-01 16:11:32
- date last changed
- 2022-01-28 18:01:12
@article{3cf87e5d-c9b2-4358-b7b5-11eab2ac472b, abstract = {{Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17){MoO}(8)center dot 10thf center dot hexane, where {MoO}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [{(MoO)-O-IV(S'(2))} {(MoO)-O-V(S'(2))}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.}}, author = {{Behrens, A and Behrens, U and Nordlander, Ebbe and Bader, C and Rehder, D}}, issn = {{0020-1693}}, keywords = {{molybdopterin; molybdenum complexes; thiofunctional ligands; oxotransferases}}, language = {{eng}}, number = {{6}}, pages = {{1970--1974}}, publisher = {{Elsevier}}, series = {{Inorganica Chimica Acta}}, title = {{Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands}}, url = {{http://dx.doi.org/10.1016/j.ica.2004.12.039}}, doi = {{10.1016/j.ica.2004.12.039}}, volume = {{358}}, year = {{2005}}, }