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Two size regimes of methanol clusters produced by adiabatic expansion

Bergersen, H. ; Abu-samha, M. ; Lindblad, A. ; Marinho, R. R. T. ; Ohrwall, G. ; Tchaplyguine, Maxim LU ; Borve, K. J. ; Svensson, S. and Bjorneholm, O. (2006) In Journal of Chemical Physics 125(18).
Abstract
Free neutral methanol clusters produced by adiabatic expansion have been studied by photoelectron spectroscopy and line shape modeling. The results show that clusters belonging to two distinct size regimes can be produced by changing the expansion conditions. While the larger size regime can be well described by line shapes calculated for clusters consisting of hundreds of molecules, the smaller size regime corresponds to methanol oligomers, predominantly of cyclic structure. There is little contribution from dimers to the spectra.
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organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Chemical Physics
volume
125
issue
18
publisher
American Institute of Physics (AIP)
external identifiers
  • wos:000242002400020
  • scopus:33751021656
  • pmid:17115748
ISSN
0021-9606
DOI
10.1063/1.2378708
language
English
LU publication?
yes
id
3e8be090-03d0-4f0c-ac79-68f7feb9dd48 (old id 377001)
date added to LUP
2016-04-01 12:33:28
date last changed
2020-01-12 10:03:01
@article{3e8be090-03d0-4f0c-ac79-68f7feb9dd48,
  abstract     = {Free neutral methanol clusters produced by adiabatic expansion have been studied by photoelectron spectroscopy and line shape modeling. The results show that clusters belonging to two distinct size regimes can be produced by changing the expansion conditions. While the larger size regime can be well described by line shapes calculated for clusters consisting of hundreds of molecules, the smaller size regime corresponds to methanol oligomers, predominantly of cyclic structure. There is little contribution from dimers to the spectra.},
  author       = {Bergersen, H. and Abu-samha, M. and Lindblad, A. and Marinho, R. R. T. and Ohrwall, G. and Tchaplyguine, Maxim and Borve, K. J. and Svensson, S. and Bjorneholm, O.},
  issn         = {0021-9606},
  language     = {eng},
  number       = {18},
  publisher    = {American Institute of Physics (AIP)},
  series       = {Journal of Chemical Physics},
  title        = {Two size regimes of methanol clusters produced by adiabatic expansion},
  url          = {http://dx.doi.org/10.1063/1.2378708},
  doi          = {10.1063/1.2378708},
  volume       = {125},
  year         = {2006},
}