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Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation.

Mitra, Mainak LU ; Lloret-Fillol, Julio; Haukka, Matti; Costas, Miquel and Nordlander, Ebbe LU (2014) In Chemical Communications 50(12). p.1408-1410
Abstract
A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Communications
volume
50
issue
12
pages
1408 - 1410
publisher
Royal Society of Chemistry
external identifiers
  • wos:000329925900002
  • pmid:24270942
  • scopus:84892609738
ISSN
1364-548X
DOI
10.1039/c3cc47830k
language
English
LU publication?
yes
id
f85e3012-5766-443b-a1ec-56255639a76d (old id 4178960)
date added to LUP
2013-12-03 17:19:01
date last changed
2017-10-01 03:02:21
@article{f85e3012-5766-443b-a1ec-56255639a76d,
  abstract     = {A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.},
  author       = {Mitra, Mainak and Lloret-Fillol, Julio and Haukka, Matti and Costas, Miquel and Nordlander, Ebbe},
  issn         = {1364-548X},
  language     = {eng},
  number       = {12},
  pages        = {1408--1410},
  publisher    = {Royal Society of Chemistry},
  series       = {Chemical Communications},
  title        = {Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation.},
  url          = {http://dx.doi.org/10.1039/c3cc47830k},
  volume       = {50},
  year         = {2014},
}