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Expanding the scope of Lewis acid catalysis in water: Remarkable ligand acceleration of aqueous ytterbium triflate catalyzed Michael addition reactions

Ding, Rui LU ; Katebzadeh, Kambiz LU ; Roman, L ; Bergquist, Karl-Erik LU and Lindström, Ulf LU (2006) In Journal of Organic Chemistry 71(1). p.352-355
Abstract
Significant rate acceleration of metal-catalyzed Michael addition reactions in water was observed upon addition of small, dibasic ligands. Ytterbium triflate and TMEDA was the most effective combination leading to a nearly 20-fold faster reaction than in the absence of ligand.
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Organic Chemistry
volume
71
issue
1
pages
352 - 355
publisher
The American Chemical Society (ACS)
external identifiers
  • pmid:16388657
  • wos:000234438700048
  • scopus:31144441931
ISSN
1520-6904
DOI
10.1021/jo051540n
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Department of Chemistry (011001220)
id
44fa5fa1-27b8-4220-95f1-5f9e5d47c55b (old id 421499)
date added to LUP
2016-04-01 12:19:30
date last changed
2021-09-29 02:00:45
@article{44fa5fa1-27b8-4220-95f1-5f9e5d47c55b,
  abstract     = {Significant rate acceleration of metal-catalyzed Michael addition reactions in water was observed upon addition of small, dibasic ligands. Ytterbium triflate and TMEDA was the most effective combination leading to a nearly 20-fold faster reaction than in the absence of ligand.},
  author       = {Ding, Rui and Katebzadeh, Kambiz and Roman, L and Bergquist, Karl-Erik and Lindström, Ulf},
  issn         = {1520-6904},
  language     = {eng},
  number       = {1},
  pages        = {352--355},
  publisher    = {The American Chemical Society (ACS)},
  series       = {Journal of Organic Chemistry},
  title        = {Expanding the scope of Lewis acid catalysis in water: Remarkable ligand acceleration of aqueous ytterbium triflate catalyzed Michael addition reactions},
  url          = {http://dx.doi.org/10.1021/jo051540n},
  doi          = {10.1021/jo051540n},
  volume       = {71},
  year         = {2006},
}