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Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis.

Abdel-Magied, Ahmed; Singh, Amrendra LU ; Haukka, Matti; Richmond, Michael G and Nordlander, Ebbe LU (2014) In Chemical Communications 50(57). p.7705-7708
Abstract
Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Communications
volume
50
issue
57
pages
7705 - 7708
publisher
Royal Society of Chemistry
external identifiers
  • pmid:24901302
  • wos:000338234000036
  • scopus:84903183517
ISSN
1364-548X
DOI
10.1039/c4cc02319f
language
English
LU publication?
yes
id
4c6e4d4c-9ddf-4aa9-95fb-c7eec2be00f6 (old id 4529156)
date added to LUP
2014-08-08 16:13:25
date last changed
2017-01-15 03:15:35
@article{4c6e4d4c-9ddf-4aa9-95fb-c7eec2be00f6,
  abstract     = {Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.},
  author       = {Abdel-Magied, Ahmed and Singh, Amrendra and Haukka, Matti and Richmond, Michael G and Nordlander, Ebbe},
  issn         = {1364-548X},
  language     = {eng},
  number       = {57},
  pages        = {7705--7708},
  publisher    = {Royal Society of Chemistry},
  series       = {Chemical Communications},
  title        = {Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis.},
  url          = {http://dx.doi.org/10.1039/c4cc02319f},
  volume       = {50},
  year         = {2014},
}