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Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis.

Abdel-Magied, Ahmed ; Singh, Amrendra LU ; Haukka, Matti ; Richmond, Michael G and Nordlander, Ebbe LU (2014) In Chemical Communications 50(57). p.7705-7708
Abstract
Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Communications
volume
50
issue
57
pages
7705 - 7708
publisher
Royal Society of Chemistry
external identifiers
  • pmid:24901302
  • wos:000338234000036
  • scopus:84903183517
  • pmid:24901302
ISSN
1364-548X
DOI
10.1039/c4cc02319f
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
4c6e4d4c-9ddf-4aa9-95fb-c7eec2be00f6 (old id 4529156)
date added to LUP
2016-04-01 10:43:40
date last changed
2022-02-17 20:49:29
@article{4c6e4d4c-9ddf-4aa9-95fb-c7eec2be00f6,
  abstract     = {{Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.}},
  author       = {{Abdel-Magied, Ahmed and Singh, Amrendra and Haukka, Matti and Richmond, Michael G and Nordlander, Ebbe}},
  issn         = {{1364-548X}},
  language     = {{eng}},
  number       = {{57}},
  pages        = {{7705--7708}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{Chemical Communications}},
  title        = {{Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis.}},
  url          = {{http://dx.doi.org/10.1039/c4cc02319f}},
  doi          = {{10.1039/c4cc02319f}},
  volume       = {{50}},
  year         = {{2014}},
}