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Mononuclear complexes and a coordination polymer of the 2-pyridylamino ((NHPy)-Py-2) functionalized P(V) ligand

Pal, Souvik; Jana, Partha LU and Nayek, Hari Pada (2014) In RSC Advances 4(51). p.26902-26906
Abstract
Three mononuclear metal complexes, [{PO2((NHPy)-Py-2)(2)}(2)M] [Py-2 - 2-pyridyl; M - Zn (1), Ni (2), Co (3)], have been synthesized by reacting metal nitrates with tetrakis(2-pyridylamino)phosphonium chloride, [P((NHPy)-Py-2)(4)]Cl, under solvothermal reaction conditions. The ligand, [P((NHPy)-Py-2)(4)]Cl, is hydrolyzed in the reaction medium. All of the complexes are isostructural and show an octahedral geometry around the metal ion. A coordination polymer, [{P((NHPy)-Py-2)(4)Cu2Cl4}ClO4](infinity) (4), was also obtained by treating [P((NHPy)-Py-2)(4)]Cl with copper perchlorate hexahydrate at ambient temperature. All of the complexes were characterized by standard analytical techniques. The solid-state structures of 1-4 were established... (More)
Three mononuclear metal complexes, [{PO2((NHPy)-Py-2)(2)}(2)M] [Py-2 - 2-pyridyl; M - Zn (1), Ni (2), Co (3)], have been synthesized by reacting metal nitrates with tetrakis(2-pyridylamino)phosphonium chloride, [P((NHPy)-Py-2)(4)]Cl, under solvothermal reaction conditions. The ligand, [P((NHPy)-Py-2)(4)]Cl, is hydrolyzed in the reaction medium. All of the complexes are isostructural and show an octahedral geometry around the metal ion. A coordination polymer, [{P((NHPy)-Py-2)(4)Cu2Cl4}ClO4](infinity) (4), was also obtained by treating [P((NHPy)-Py-2)(4)]Cl with copper perchlorate hexahydrate at ambient temperature. All of the complexes were characterized by standard analytical techniques. The solid-state structures of 1-4 were established by single crystal X-ray diffraction analysis. The optical properties of 1-4 have been investigated. (Less)
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
RSC Advances
volume
4
issue
51
pages
26902 - 26906
publisher
Royal Society of Chemistry
external identifiers
  • wos:000338640200044
  • scopus:84903649588
ISSN
2046-2069
DOI
10.1039/c4ra02258k
language
English
LU publication?
yes
id
1260b7ed-129c-4570-97e7-bc910f2bfdf4 (old id 4602540)
date added to LUP
2014-09-04 16:05:56
date last changed
2017-01-01 05:30:17
@article{1260b7ed-129c-4570-97e7-bc910f2bfdf4,
  abstract     = {Three mononuclear metal complexes, [{PO2((NHPy)-Py-2)(2)}(2)M] [Py-2 - 2-pyridyl; M - Zn (1), Ni (2), Co (3)], have been synthesized by reacting metal nitrates with tetrakis(2-pyridylamino)phosphonium chloride, [P((NHPy)-Py-2)(4)]Cl, under solvothermal reaction conditions. The ligand, [P((NHPy)-Py-2)(4)]Cl, is hydrolyzed in the reaction medium. All of the complexes are isostructural and show an octahedral geometry around the metal ion. A coordination polymer, [{P((NHPy)-Py-2)(4)Cu2Cl4}ClO4](infinity) (4), was also obtained by treating [P((NHPy)-Py-2)(4)]Cl with copper perchlorate hexahydrate at ambient temperature. All of the complexes were characterized by standard analytical techniques. The solid-state structures of 1-4 were established by single crystal X-ray diffraction analysis. The optical properties of 1-4 have been investigated.},
  author       = {Pal, Souvik and Jana, Partha and Nayek, Hari Pada},
  issn         = {2046-2069},
  language     = {eng},
  number       = {51},
  pages        = {26902--26906},
  publisher    = {Royal Society of Chemistry},
  series       = {RSC Advances},
  title        = {Mononuclear complexes and a coordination polymer of the 2-pyridylamino ((NHPy)-Py-2) functionalized P(V) ligand},
  url          = {http://dx.doi.org/10.1039/c4ra02258k},
  volume       = {4},
  year         = {2014},
}