Mononuclear complexes and a coordination polymer of the 2-pyridylamino ((NHPy)-Py-2) functionalized P(V) ligand
(2014) In RSC Advances 4(51). p.26902-26906- Abstract
- Three mononuclear metal complexes, [{PO2((NHPy)-Py-2)(2)}(2)M] [Py-2 - 2-pyridyl; M - Zn (1), Ni (2), Co (3)], have been synthesized by reacting metal nitrates with tetrakis(2-pyridylamino)phosphonium chloride, [P((NHPy)-Py-2)(4)]Cl, under solvothermal reaction conditions. The ligand, [P((NHPy)-Py-2)(4)]Cl, is hydrolyzed in the reaction medium. All of the complexes are isostructural and show an octahedral geometry around the metal ion. A coordination polymer, [{P((NHPy)-Py-2)(4)Cu2Cl4}ClO4](infinity) (4), was also obtained by treating [P((NHPy)-Py-2)(4)]Cl with copper perchlorate hexahydrate at ambient temperature. All of the complexes were characterized by standard analytical techniques. The solid-state structures of 1-4 were established... (More)
- Three mononuclear metal complexes, [{PO2((NHPy)-Py-2)(2)}(2)M] [Py-2 - 2-pyridyl; M - Zn (1), Ni (2), Co (3)], have been synthesized by reacting metal nitrates with tetrakis(2-pyridylamino)phosphonium chloride, [P((NHPy)-Py-2)(4)]Cl, under solvothermal reaction conditions. The ligand, [P((NHPy)-Py-2)(4)]Cl, is hydrolyzed in the reaction medium. All of the complexes are isostructural and show an octahedral geometry around the metal ion. A coordination polymer, [{P((NHPy)-Py-2)(4)Cu2Cl4}ClO4](infinity) (4), was also obtained by treating [P((NHPy)-Py-2)(4)]Cl with copper perchlorate hexahydrate at ambient temperature. All of the complexes were characterized by standard analytical techniques. The solid-state structures of 1-4 were established by single crystal X-ray diffraction analysis. The optical properties of 1-4 have been investigated. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/4602540
- author
- Pal, Souvik ; Jana, Partha LU and Nayek, Hari Pada
- organization
- publishing date
- 2014
- type
- Contribution to journal
- publication status
- published
- subject
- in
- RSC Advances
- volume
- 4
- issue
- 51
- pages
- 26902 - 26906
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000338640200044
- scopus:84903649588
- ISSN
- 2046-2069
- DOI
- 10.1039/c4ra02258k
- language
- English
- LU publication?
- yes
- id
- 1260b7ed-129c-4570-97e7-bc910f2bfdf4 (old id 4602540)
- date added to LUP
- 2016-04-01 13:10:06
- date last changed
- 2022-01-27 17:45:22
@article{1260b7ed-129c-4570-97e7-bc910f2bfdf4,
abstract = {{Three mononuclear metal complexes, [{PO2((NHPy)-Py-2)(2)}(2)M] [Py-2 - 2-pyridyl; M - Zn (1), Ni (2), Co (3)], have been synthesized by reacting metal nitrates with tetrakis(2-pyridylamino)phosphonium chloride, [P((NHPy)-Py-2)(4)]Cl, under solvothermal reaction conditions. The ligand, [P((NHPy)-Py-2)(4)]Cl, is hydrolyzed in the reaction medium. All of the complexes are isostructural and show an octahedral geometry around the metal ion. A coordination polymer, [{P((NHPy)-Py-2)(4)Cu2Cl4}ClO4](infinity) (4), was also obtained by treating [P((NHPy)-Py-2)(4)]Cl with copper perchlorate hexahydrate at ambient temperature. All of the complexes were characterized by standard analytical techniques. The solid-state structures of 1-4 were established by single crystal X-ray diffraction analysis. The optical properties of 1-4 have been investigated.}},
author = {{Pal, Souvik and Jana, Partha and Nayek, Hari Pada}},
issn = {{2046-2069}},
language = {{eng}},
number = {{51}},
pages = {{26902--26906}},
publisher = {{Royal Society of Chemistry}},
series = {{RSC Advances}},
title = {{Mononuclear complexes and a coordination polymer of the 2-pyridylamino ((NHPy)-Py-2) functionalized P(V) ligand}},
url = {{http://dx.doi.org/10.1039/c4ra02258k}},
doi = {{10.1039/c4ra02258k}},
volume = {{4}},
year = {{2014}},
}