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An investigation of combustion properties of a gasoline primary reference fuel surrogate blended with butanol

Richter, Sandra ; Braun-Unkhoff, Marina ; Herzler, Jürgen ; Methling, Torsten LU ; Naumann, Clemens and Riedel, Uwe (2019) ASME Turbo Expo 2019: Turbomachinery Technical Conference and Exposition, GT 2019 In Proceedings of the ASME Turbo Expo 3.
Abstract

Currently, many research studies are exploring opportunities for the use of novel fuels and of their blends with conventional, i.e. petroleum-based fuels. To pave the way for their acceptance and implementation in the existing energy market, a comprehensive knowledge about their combustion properties is inevitable, among others. Within this context, alcohols, with butanol in particular, are considered as attractive candidates for the needed de-fossilization of the energy sector. In this work, we report on the oxidation of mixtures of n-heptane/i-octane (PRF90, primary reference fuel, a gasoline surrogat e) and addition of n-butanol, 20% and 40%, respectively, in a combined experimental and modeling effort. The focus was set on two... (More)

Currently, many research studies are exploring opportunities for the use of novel fuels and of their blends with conventional, i.e. petroleum-based fuels. To pave the way for their acceptance and implementation in the existing energy market, a comprehensive knowledge about their combustion properties is inevitable, among others. Within this context, alcohols, with butanol in particular, are considered as attractive candidates for the needed de-fossilization of the energy sector. In this work, we report on the oxidation of mixtures of n-heptane/i-octane (PRF90, primary reference fuel, a gasoline surrogat e) and addition of n-butanol, 20% and 40%, respectively, in a combined experimental and modeling effort. The focus was set on two fundamental combustion properties: (i) Ignition delay times measured in a shock tube, at ambient and elevated pressures, for stoichiometric mixtures, and (ii) Laminar burning velocities, at ambient and elevated pressures. Moreover, two detailed chemical kinetic reaction mechanisms, with an in-house model among them, have been used for investigating and analyzing the combustion of these mixtures. In general, the experimental data agree well with the model predictions of the in-house reaction model, for the temperatures, pressures, and fuel-air ratios studied. Room for improvements is seen for PRF90. The results achieved were also compared to those of n-butanol reported recently; the findings demonstrated clearly the effect of the n-butanol sub model on binary fuel-air mixtures consisting of PRF and n-butanol. From the present work it can be concluded that the addition of n-butanol to gasoline appears to be an attractive alternative fuel for most types of heat engines.

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Please use this url to cite or link to this publication:
author
; ; ; ; and
organization
publishing date
type
Chapter in Book/Report/Conference proceeding
publication status
published
subject
keywords
Alternative fuels, Butanol, Gasoline, Ignition delay time, Laminar flame speed, PRF90, Reaction mechanism]
host publication
Coal, Biomass, Hydrogen, and Alternative Fuels; Cycle Innovations; Electric Power; Industrial and Cogeneration; Organic Rankine Cycle Power Systems
series title
Proceedings of the ASME Turbo Expo
volume
3
article number
GT2019-90911
publisher
American Society Of Mechanical Engineers (ASME)
conference name
ASME Turbo Expo 2019: Turbomachinery Technical Conference and Exposition, GT 2019
conference location
Phoenix, United States
conference dates
2019-06-17 - 2019-06-21
external identifiers
  • scopus:85075468996
ISBN
9780791858608
DOI
10.1115/GT2019-90911
language
English
LU publication?
yes
id
466cc46f-7ab7-4ca3-84c1-04da5cf33fa4
date added to LUP
2019-12-09 13:13:11
date last changed
2022-04-18 19:12:28
@inproceedings{466cc46f-7ab7-4ca3-84c1-04da5cf33fa4,
  abstract     = {{<p>Currently, many research studies are exploring opportunities for the use of novel fuels and of their blends with conventional, i.e. petroleum-based fuels. To pave the way for their acceptance and implementation in the existing energy market, a comprehensive knowledge about their combustion properties is inevitable, among others. Within this context, alcohols, with butanol in particular, are considered as attractive candidates for the needed de-fossilization of the energy sector. In this work, we report on the oxidation of mixtures of n-heptane/i-octane (PRF90, primary reference fuel, a gasoline surrogat e) and addition of n-butanol, 20% and 40%, respectively, in a combined experimental and modeling effort. The focus was set on two fundamental combustion properties: (i) Ignition delay times measured in a shock tube, at ambient and elevated pressures, for stoichiometric mixtures, and (ii) Laminar burning velocities, at ambient and elevated pressures. Moreover, two detailed chemical kinetic reaction mechanisms, with an in-house model among them, have been used for investigating and analyzing the combustion of these mixtures. In general, the experimental data agree well with the model predictions of the in-house reaction model, for the temperatures, pressures, and fuel-air ratios studied. Room for improvements is seen for PRF90. The results achieved were also compared to those of n-butanol reported recently; the findings demonstrated clearly the effect of the n-butanol sub model on binary fuel-air mixtures consisting of PRF and n-butanol. From the present work it can be concluded that the addition of n-butanol to gasoline appears to be an attractive alternative fuel for most types of heat engines.</p>}},
  author       = {{Richter, Sandra and Braun-Unkhoff, Marina and Herzler, Jürgen and Methling, Torsten and Naumann, Clemens and Riedel, Uwe}},
  booktitle    = {{Coal, Biomass, Hydrogen, and Alternative Fuels; Cycle Innovations; Electric Power; Industrial and Cogeneration; Organic Rankine Cycle Power Systems}},
  isbn         = {{9780791858608}},
  keywords     = {{Alternative fuels; Butanol; Gasoline; Ignition delay time; Laminar flame speed; PRF90; Reaction mechanism]}},
  language     = {{eng}},
  publisher    = {{American Society Of Mechanical Engineers (ASME)}},
  series       = {{Proceedings of the ASME Turbo Expo}},
  title        = {{An investigation of combustion properties of a gasoline primary reference fuel surrogate blended with butanol}},
  url          = {{http://dx.doi.org/10.1115/GT2019-90911}},
  doi          = {{10.1115/GT2019-90911}},
  volume       = {{3}},
  year         = {{2019}},
}