The influence of nanoparticles on enzymatic bioelectrocatalysis
(2014) In RSC Advances 4(72). p.38164-38168- Abstract
- In nearly all papers concerning enzyme-nanoparticle based bio-electronic devices, it is stated that the presence of nanoparticles on electrode surfaces per se enhances bioelectrocatalysis, although the reasons for that enhancement are often unclear. Here, we report detailed experimental evidence that neither an overpotential of bioelectrocatalysis, nor direct electron transfer and bioelectrocatalytic reaction rates for an adsorbed enzyme depend on the size of nanoparticles within the range of 20-80 nm, i.e. for nanoparticles that are considerably larger than the enzyme molecules.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/4717126
- author
- Pankratov, Dmitry
; Sundberg, Richard
LU
; Suyatin, Dmitry
LU
; Sotres, Javier ; Barrantes, Alejandro ; Ruzgas, Tautgirdas ; Maximov, Ivan LU
; Montelius, Lars LU and Shleev, Sergey
- organization
- publishing date
- 2014
- type
- Contribution to journal
- publication status
- published
- subject
- in
- RSC Advances
- volume
- 4
- issue
- 72
- pages
- 38164 - 38168
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000341455200030
- scopus:84906872032
- ISSN
- 2046-2069
- DOI
- 10.1039/c4ra08107b
- language
- English
- LU publication?
- yes
- id
- 3ed9da7e-c7fc-4ff2-8249-57c06652b850 (old id 4717126)
- date added to LUP
- 2016-04-01 14:47:53
- date last changed
- 2024-10-10 21:45:25
@article{3ed9da7e-c7fc-4ff2-8249-57c06652b850, abstract = {{In nearly all papers concerning enzyme-nanoparticle based bio-electronic devices, it is stated that the presence of nanoparticles on electrode surfaces per se enhances bioelectrocatalysis, although the reasons for that enhancement are often unclear. Here, we report detailed experimental evidence that neither an overpotential of bioelectrocatalysis, nor direct electron transfer and bioelectrocatalytic reaction rates for an adsorbed enzyme depend on the size of nanoparticles within the range of 20-80 nm, i.e. for nanoparticles that are considerably larger than the enzyme molecules.}}, author = {{Pankratov, Dmitry and Sundberg, Richard and Suyatin, Dmitry and Sotres, Javier and Barrantes, Alejandro and Ruzgas, Tautgirdas and Maximov, Ivan and Montelius, Lars and Shleev, Sergey}}, issn = {{2046-2069}}, language = {{eng}}, number = {{72}}, pages = {{38164--38168}}, publisher = {{Royal Society of Chemistry}}, series = {{RSC Advances}}, title = {{The influence of nanoparticles on enzymatic bioelectrocatalysis}}, url = {{http://dx.doi.org/10.1039/c4ra08107b}}, doi = {{10.1039/c4ra08107b}}, volume = {{4}}, year = {{2014}}, }