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Substrate-selective catalysis.

Lindbäck, Emil LU ; Dawaigher, Sami LU and Wärnmark, Kenneth LU (2014) In Chemistry: A European Journal 20(42). p.13432-13481
Abstract
Substrate selectivity is an important output function for the validation of different enzyme models, catalytic cavity compounds, and reaction mechanisms as demonstrated in this review. In contrast to stereo-, regio-, and chemoselective catalysis, the field of substrate-selective catalysis is under-researched and has to date generated only a few, but important, industrial applications. This review points out the broad spectrum of different reaction types that have been investigated in substrate-selective catalysis. The present review is the first one covering substrate-selective catalysis and deals with reactions in which the substrates involved have the same reacting functionality and the catalysts is used in catalytic or in stoichiometric... (More)
Substrate selectivity is an important output function for the validation of different enzyme models, catalytic cavity compounds, and reaction mechanisms as demonstrated in this review. In contrast to stereo-, regio-, and chemoselective catalysis, the field of substrate-selective catalysis is under-researched and has to date generated only a few, but important, industrial applications. This review points out the broad spectrum of different reaction types that have been investigated in substrate-selective catalysis. The present review is the first one covering substrate-selective catalysis and deals with reactions in which the substrates involved have the same reacting functionality and the catalysts is used in catalytic or in stoichiometric amounts. The review covers real substrate-selective catalysis, thus only including cases in which substrate-selective catalysis has been observed in competition between substrates. (Less)
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemistry: A European Journal
volume
20
issue
42
pages
13432 - 13481
publisher
John Wiley & Sons
external identifiers
  • pmid:25279721
  • wos:000342797500003
ISSN
1521-3765
DOI
10.1002/chem.201402548
language
English
LU publication?
yes
id
07a0e613-ca13-413d-9c03-d69e8b2cd67b (old id 4738401)
date added to LUP
2014-11-17 11:33:41
date last changed
2016-09-30 05:34:33
@article{07a0e613-ca13-413d-9c03-d69e8b2cd67b,
  abstract     = {Substrate selectivity is an important output function for the validation of different enzyme models, catalytic cavity compounds, and reaction mechanisms as demonstrated in this review. In contrast to stereo-, regio-, and chemoselective catalysis, the field of substrate-selective catalysis is under-researched and has to date generated only a few, but important, industrial applications. This review points out the broad spectrum of different reaction types that have been investigated in substrate-selective catalysis. The present review is the first one covering substrate-selective catalysis and deals with reactions in which the substrates involved have the same reacting functionality and the catalysts is used in catalytic or in stoichiometric amounts. The review covers real substrate-selective catalysis, thus only including cases in which substrate-selective catalysis has been observed in competition between substrates.},
  author       = {Lindbäck, Emil and Dawaigher, Sami and Wärnmark, Kenneth},
  issn         = {1521-3765},
  language     = {eng},
  number       = {42},
  pages        = {13432--13481},
  publisher    = {John Wiley & Sons},
  series       = {Chemistry: A European Journal},
  title        = {Substrate-selective catalysis.},
  url          = {http://dx.doi.org/10.1002/chem.201402548},
  volume       = {20},
  year         = {2014},
}